Electrochemical properties of Rubpy-reduced graphene oxide synergized by ultrasonication for label-free quercetin sensing
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Arumugasamy, Shiva Kumar | - |
dc.contributor.author | Kanagavalli, Pandiayaraj | - |
dc.contributor.author | Veerapandian, Murugan | - |
dc.contributor.author | Jayaraman, Mathiyarasu | - |
dc.contributor.author | Yun, Kyusik | - |
dc.date.available | 2020-12-09T00:40:27Z | - |
dc.date.created | 2020-12-09 | - |
dc.date.issued | 2021-01 | - |
dc.identifier.issn | 0169-4332 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/gachon/handle/2020.sw.gachon/79211 | - |
dc.description.abstract | Tuning the interfacial properties of oxygenated graphene and reduced graphene oxide (rGO) with optical/electrochemically active molecules are highly useful for sensor studies. Herein, we demonstrate the ultra-sonochemical mediated simultaneous reduction of oxygenated graphene and adsorption of ruthenium bipyridine complex (Rubpy) on the planes of rGO nanosheets. Different weight percentage ratio of Rubpy was decorated on the planes of rGO by simple alteration in the sonication parameters. Intercalation of Rubpy complex influences the electron cloud of inherent graphitic carbon network and intermolecular oxygenated functional moieties on the rGO matrix. Activation of C=N network derived from bipyridine ligands of organometallic coordination compound, Rubpy, on the rGO planes enable an amplified electron mobility at the interface of electrode beneficial for electrocatalytic analysis. rGO-Rubpy modified electrode enabled direct electrochemical redox reaction of quercetin, exhibiting a linear detection range of 0.05-50 mu M, with a lowest detection limit of 0.002 mu M. Demonstrated label-free sensor platform display selectivity toward quercetin even in the presence of interferents and sensitivity in the real sample, promising for complementary analytical application. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER | - |
dc.relation.isPartOf | APPLIED SURFACE SCIENCE | - |
dc.title | Electrochemical properties of Rubpy-reduced graphene oxide synergized by ultrasonication for label-free quercetin sensing | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.description.journalClass | 1 | - |
dc.identifier.wosid | 000582798700009 | - |
dc.identifier.doi | 10.1016/j.apsusc.2020.147777 | - |
dc.identifier.bibliographicCitation | APPLIED SURFACE SCIENCE, v.537 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.scopusid | 2-s2.0-85090953071 | - |
dc.citation.title | APPLIED SURFACE SCIENCE | - |
dc.citation.volume | 537 | - |
dc.contributor.affiliatedAuthor | Arumugasamy, Shiva Kumar | - |
dc.contributor.affiliatedAuthor | Yun, Kyusik | - |
dc.type.docType | Article | - |
dc.subject.keywordAuthor | Ultrasonochemical surface modification | - |
dc.subject.keywordAuthor | Rubpy intercalation | - |
dc.subject.keywordAuthor | rGO sensitization | - |
dc.subject.keywordAuthor | Opto-electrochemical material | - |
dc.subject.keywordAuthor | Quercetin redox reaction | - |
dc.subject.keywordPlus | ULTRASOUND-ASSISTED SYNTHESIS | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordPlus | ELECTROCHEMILUMINESCENCE | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | ELECTRODE | - |
dc.subject.keywordPlus | PLATFORM | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Coatings & Films | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
1342, Seongnam-daero, Sujeong-gu, Seongnam-si, Gyeonggi-do, Republic of Korea(13120)031-750-5114
COPYRIGHT 2020 Gachon University All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.