Compositional Engineering of FAPbI(3) Perovskite Added MACl with MAPbBr(3) or FAPbBr(3)
- Authors
- Joo, Sung Hwan; Choi, Hyung Wook
- Issue Date
- Oct-2021
- Publisher
- MDPI
- Keywords
- FAPbBr3; FAPbI3; MACl; Perovskite solar cells
- Citation
- Coatings, v.11, no.10
- Journal Title
- Coatings
- Volume
- 11
- Number
- 10
- URI
- https://scholarworks.bwise.kr/gachon/handle/2020.sw.gachon/82646
- DOI
- 10.3390/coatings11101184
- ISSN
- 2079-6412
- Abstract
- Many attempts have been made to stabilize α-phase formamidinium lead iodide (α-FAPbI3 ) using mixed cations or anions with MA+, FA+, Br− and I− . A representative method is to stably produce α-FAPbI3 by adding methylammonium lead (MAPbBr3 ) to the light absorption layer of a perovskite solar cell and using methylammonium chloride (MACl) as an additive. However, in the perovskite containing MA+ and Br−, the current density is lowered due to an unwanted increase in the bandgap; phase separation occurs due to the mixing of halides, and thermal stability is lowered. Therefore, in this study, in order to minimize the decrease in the composition ratio of FAPbI3 and to reduce MA+, the addition amount of MACl was first optimized. Thereafter, a new attempt was made to fabricate FAPbI3 perovskite by using formamidinium lead bromide (FAPbBr3 ) and MACl together as phase stabilizers instead of MAPbBr3 . As for the FAPbI3-MAPbBr3 solar cell, the (FAPbI3 )0.93 (MAPbBr3 )0.07 device showed the highest efficiency. On the other hand, in the case of the FAPbI3-FAPbBr3 solar cell, the (FAPbI3 )0.99 (FAPbBr3 )0.01 solar cell with a very small FAPbBr3 composition ratio showed the highest efficiency with fast photovoltaic performance improvement and high crystallinity. In addition, the FAPbI3-FAPbBr3 solar cell showed a higher performance than the FAPbI3-MAPbBr3 solar cell, suggesting that FAPbBr3 can sufficiently replace MAPbBr3 . © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
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