A pyrimidine-5-carbonitrile acceptor combined with an ortho-linked donor for long lifetime through facilitated reverse intersystem crossing in thermally activated delayed fluorescence emitters
DC Field | Value | Language |
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dc.contributor.author | Jang, Ji Seon | - |
dc.contributor.author | Lee, Ha Lim | - |
dc.contributor.author | Lee, Kyung Hyung | - |
dc.contributor.author | Lee, Jun Yeob | - |
dc.contributor.author | Hong, Wan Pyo | - |
dc.date.accessioned | 2022-06-09T11:40:08Z | - |
dc.date.available | 2022-06-09T11:40:08Z | - |
dc.date.created | 2022-06-09 | - |
dc.date.issued | 2021-02 | - |
dc.identifier.issn | 2050-7526 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/gachon/handle/2020.sw.gachon/84586 | - |
dc.description.abstract | Molecular design of thermally activated delayed fluorescence (TADF) emitters combining a 4,6-diphenylpyrimidine-5-carbonitrile (PyCN) acceptor and an ortho-linked donor was developed in order to extend the lifetimes of the TADF organic light-emitting diodes by shortening the delayed fluorescence lifetime and facilitating the reverse intersystem crossing by a TADF process. The ortho connection of the donor to the strong PyCN acceptor reduced the singlet-triplet energy splitting to 0.02 eV and the delayed fluorescence lifetime to 2.4 mu s compared to 0.18 eV and 12.8 mu s of the corresponding para-linked TADF emitter. The PyCN-derived emitter was even better than the well-known diphenyltriazine-derived emitter in terms of TADF parameters. Moreover, a high reverse intersystem crossing rate constant close to 1.0 x 10(6) s(-1) was noticed in the PyCN derived emitter. The high reverse intersystem crossing rate suppressed efficiency roll-off and extended device lifetime. Therefore, the design strategy merging the PyCN acceptor with an ortho-linked bicarbazole donor was successful in reducing efficiency roll-off and improving lifetime. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.relation.isPartOf | JOURNAL OF MATERIALS CHEMISTRY C | - |
dc.title | A pyrimidine-5-carbonitrile acceptor combined with an ortho-linked donor for long lifetime through facilitated reverse intersystem crossing in thermally activated delayed fluorescence emitters | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.description.journalClass | 1 | - |
dc.identifier.wosid | 000623516700020 | - |
dc.identifier.doi | 10.1039/d0tc04564k | - |
dc.identifier.bibliographicCitation | JOURNAL OF MATERIALS CHEMISTRY C, v.9, no.7, pp.2408 - 2415 | - |
dc.description.isOpenAccess | N | - |
dc.citation.endPage | 2415 | - |
dc.citation.startPage | 2408 | - |
dc.citation.title | JOURNAL OF MATERIALS CHEMISTRY C | - |
dc.citation.volume | 9 | - |
dc.citation.number | 7 | - |
dc.contributor.affiliatedAuthor | Hong, Wan Pyo | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | LIGHT-EMITTING-DIODES | - |
dc.subject.keywordPlus | EXTERNAL QUANTUM EFFICIENCY | - |
dc.subject.keywordPlus | MOLECULAR DESIGN | - |
dc.subject.keywordPlus | GREEN | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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