Elucidating the Chain-Extension Effect on the Exciton-Dissociation Mechanism through an Intra- or Interchain Polaron-Pair State in Push-Pull Conjugated Polymers
DC Field | Value | Language |
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dc.contributor.author | Lee, Dongki | - |
dc.contributor.author | Han, Se Gyo | - |
dc.contributor.author | Kim, Hyojung | - |
dc.contributor.author | Hwang, Hyeongjin | - |
dc.contributor.author | Park, Chaneui | - |
dc.contributor.author | Noh, Jaebum | - |
dc.contributor.author | Mun, Jungho | - |
dc.contributor.author | Nho, Hak-Won | - |
dc.contributor.author | Cho, Jeong Bin | - |
dc.contributor.author | Kim, Dong Hyeon | - |
dc.contributor.author | Jeong, Byeong Geun | - |
dc.contributor.author | Oh, Chang-Mok | - |
dc.contributor.author | Yoon, Taewoong | - |
dc.contributor.author | Sung, Woong | - |
dc.contributor.author | Lee, Hansol | - |
dc.contributor.author | Nah, Sanghee | - |
dc.contributor.author | Kang, Boseok | - |
dc.contributor.author | Hwang, In-Wook | - |
dc.contributor.author | Jang, Joon I. | - |
dc.contributor.author | Kwon, Oh-Hoon | - |
dc.contributor.author | Rho, Junsuk | - |
dc.contributor.author | Jeong, Mun Seok | - |
dc.contributor.author | Cho, Kilwon | - |
dc.date.accessioned | 2023-01-21T04:40:11Z | - |
dc.date.available | 2023-01-21T04:40:11Z | - |
dc.date.created | 2023-01-18 | - |
dc.date.issued | 2022-12 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/gachon/handle/2020.sw.gachon/86749 | - |
dc.description.abstract | We elucidated chain-extension effects of a benzo-dithiophene (BDT) and thienopyrroledione-based push-pull conjugated polymer (CP) on its exciton-dissociation mechanism within aggregate systems using transient absoption spectroscopy. The side-group extension CP with benzothiophene on the BDT unit induced H-type excitons with excess energy owing to decreased chain stiffness. This led to interchain polaron-pair (PP)-mediated exciton dissociation. The stiff side-group extended with thienothiophene on the BDT unit also induced H-type excitons, but the decreased energy and breadth of the density of states suppressed the interchain PP-mediated exciton dissociation. The main-chain-extension CP with two thiophenes on either side of the BDT unit has a curved structure disturbing the interchain packing. Thus, the driving force of exciton dissociation between the chains decreased, leading to intrachain PP-mediated exciton dissociation. Our findings can facilitate the development of novel CPs to further increase the efficiencies of polymer solar cells. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | CHEMISTRY OF MATERIALS | - |
dc.title | Elucidating the Chain-Extension Effect on the Exciton-Dissociation Mechanism through an Intra- or Interchain Polaron-Pair State in Push-Pull Conjugated Polymers | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.description.journalClass | 1 | - |
dc.identifier.wosid | 000893174000001 | - |
dc.identifier.doi | 10.1021/acs.chemmater.2c02175 | - |
dc.identifier.bibliographicCitation | CHEMISTRY OF MATERIALS, v.34, no.24, pp.10873 - 10884 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.scopusid | 2-s2.0-85143526520 | - |
dc.citation.endPage | 10884 | - |
dc.citation.startPage | 10873 | - |
dc.citation.title | CHEMISTRY OF MATERIALS | - |
dc.citation.volume | 34 | - |
dc.citation.number | 24 | - |
dc.contributor.affiliatedAuthor | Lee, Hansol | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | CHARGE SEPARATION | - |
dc.subject.keywordPlus | POLY(3-HEXYLTHIOPHENE) | - |
dc.subject.keywordPlus | ULTRAFAST | - |
dc.subject.keywordPlus | DYNAMICS | - |
dc.subject.keywordPlus | DELOCALIZATION | - |
dc.subject.keywordPlus | RECOMBINATION | - |
dc.subject.keywordPlus | AGGREGATION | - |
dc.subject.keywordPlus | RELAXATION | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | DIFFUSION | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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