Plastic-Derived Solid Acid Catalysts for the Production of Methyl 2-Hydroxyisobutyrate via Esterification
DC Field | Value | Language |
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dc.contributor.author | Yun, Jimin | - |
dc.contributor.author | Kim, Sangwon | - |
dc.contributor.author | Jung, Wonjong | - |
dc.contributor.author | Jung, Ji Chul | - |
dc.date.accessioned | 2024-07-27T11:30:25Z | - |
dc.date.available | 2024-07-27T11:30:25Z | - |
dc.date.issued | 2024-08 | - |
dc.identifier.issn | 0256-1115 | - |
dc.identifier.issn | 1975-7220 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/gachon/handle/2020.sw.gachon/92084 | - |
dc.description.abstract | In this study, we successfully prepare solid acid catalysts using plastic as the starting material for the production of methyl 2-hydroxyisobutyrate (HBM) through the esterification of 2-hydroxyisobutyric acid (HBA) and methanol. Polyethylene (PE) and polyvinyl chloride (PVC) are sulfonated at different temperatures (X) to obtain sulfonated polymer catalysts (SPE_X and SPVC_X). Various characterizations clearly confirm the introduction of sulfonic acid groups (-SO3H groups), which serve as active sites in this reaction, on the PE and PVC surfaces via sulfonation. For the SPVC_X catalysts, an excessively high sulfonation temperature facilitate the loss of chlorine groups (-Cl groups) via dehydrochlorination, resulting in a decrease in catalytic activity. In particular, the -Cl groups improve the acidic properties and accessibility of reactants to the -SO3H groups of the SPVC_X catalysts, leading to a high HBM yield. Therefore, the SPVC_120 catalyst show the highest HBM yield (ca. 75%) because of the abundant -SO3H and -Cl groups on the catalyst surface. Furthermore, the catalytic performance of the SPVC_120 catalyst surpassed those of commercial ion-exchange resins such as Amberlyst-15 and Nafion NR50, which are representative solid acid catalysts for esterification. | - |
dc.format.extent | 10 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | KOREAN INSTITUTE CHEMICAL ENGINEERS | - |
dc.title | Plastic-Derived Solid Acid Catalysts for the Production of Methyl 2-Hydroxyisobutyrate via Esterification | - |
dc.type | Article | - |
dc.identifier.wosid | 001190041100001 | - |
dc.identifier.doi | 10.1007/s11814-024-00154-w | - |
dc.identifier.bibliographicCitation | KOREAN JOURNAL OF CHEMICAL ENGINEERING, v.41, no.8, pp 2297 - 2306 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.scopusid | 2-s2.0-85188147170 | - |
dc.citation.endPage | 2306 | - |
dc.citation.startPage | 2297 | - |
dc.citation.title | KOREAN JOURNAL OF CHEMICAL ENGINEERING | - |
dc.citation.volume | 41 | - |
dc.citation.number | 8 | - |
dc.type.docType | Article | - |
dc.publisher.location | 대한민국 | - |
dc.subject.keywordAuthor | Methyl 2-hydroxyisobutyrate | - |
dc.subject.keywordAuthor | 2-Hydroxyisobutyric acid | - |
dc.subject.keywordAuthor | Esterification | - |
dc.subject.keywordAuthor | Sulfonation | - |
dc.subject.keywordAuthor | Plastic-derived catalyst | - |
dc.subject.keywordPlus | POLYVINYL-CHLORIDE | - |
dc.subject.keywordPlus | AMORPHOUS-CARBON | - |
dc.subject.keywordPlus | HETEROGENEOUS CATALYST | - |
dc.subject.keywordPlus | POLY(VINYL CHLORIDE) | - |
dc.subject.keywordPlus | OLEIC-ACID | - |
dc.subject.keywordPlus | POLYETHYLENE | - |
dc.subject.keywordPlus | SULFONATION | - |
dc.subject.keywordPlus | CELLULOSE | - |
dc.subject.keywordPlus | METHANOL | - |
dc.subject.keywordPlus | FTIR | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
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