Critical Role of Functional Groups Containing N, S, and O on Graphene Surface for Stable and Fast Charging Li-S Batteries
DC Field | Value | Language |
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dc.contributor.author | Sun, Jinhua | - |
dc.contributor.author | Hwang, Jang-Yeon | - |
dc.contributor.author | Jankowski, Piotr | - |
dc.contributor.author | Xiao, Linhong | - |
dc.contributor.author | Sanchez, Jaime S. | - |
dc.contributor.author | Xia, Zhenyuan | - |
dc.contributor.author | Lee, Suyeong | - |
dc.contributor.author | Talyzin, Alexandr V. | - |
dc.contributor.author | Matic, Aleksandar | - |
dc.contributor.author | Palermo, Vincenzo | - |
dc.contributor.author | Sun, Yang-Kook | - |
dc.contributor.author | Agostini, Marco | - |
dc.date.accessioned | 2021-07-30T04:45:05Z | - |
dc.date.available | 2021-07-30T04:45:05Z | - |
dc.date.created | 2021-07-14 | - |
dc.date.issued | 2021-04 | - |
dc.identifier.issn | 1613-6810 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/1244 | - |
dc.description.abstract | Lithium-sulfur (Li-S) batteries are considered one of the most promising energy storage technologies, possibly replacing the state-of-the-art lithium-ion (Li-ion) batteries owing to their high energy density, low cost, and eco-compatibility. However, the migration of high-order lithium polysulfides (LiPs) to the lithium surface and the sluggish electrochemical kinetics pose challenges to their commercialization. The interactions between the cathode and LiPs can be enhanced by the doping of the carbon host with heteroatoms, however with relatively low doping content (<10%) in the bulk of the carbon, which can hardly interact with LiPs at the host surface. In this study, the grafting of versatile functional groups with designable properties (e.g., catalytic effects) directly on the surface of the carbon host is proposed to enhance interactions with LiPs. As model systems, benzene groups containing N/O and S/O atoms are vertically grafted and uniformly distributed on the surface of expanded reduced graphene oxide, fostering a stable interface between the cathode and LiPs. The combination of experiments and density functional theory calculations demonstrate improvements in chemical interactions between graphene and LiPs, with an enhancement in the electrochemical kinetics, power, and energy densities. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Critical Role of Functional Groups Containing N, S, and O on Graphene Surface for Stable and Fast Charging Li-S Batteries | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Sun, Yang-Kook | - |
dc.identifier.doi | 10.1002/smll.202007242 | - |
dc.identifier.scopusid | 2-s2.0-85102478732 | - |
dc.identifier.wosid | 000628740800001 | - |
dc.identifier.bibliographicCitation | SMALL, v.17, no.17, pp.1 - 10 | - |
dc.relation.isPartOf | SMALL | - |
dc.citation.title | SMALL | - |
dc.citation.volume | 17 | - |
dc.citation.number | 17 | - |
dc.citation.startPage | 1 | - |
dc.citation.endPage | 10 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | Y | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | Cathodes | - |
dc.subject.keywordPlus | Charging (batteries) | - |
dc.subject.keywordPlus | Costs | - |
dc.subject.keywordPlus | Density functional theory | - |
dc.subject.keywordPlus | Electrolytes | - |
dc.subject.keywordPlus | Grafting (chemical) | - |
dc.subject.keywordPlus | Lithium compounds | - |
dc.subject.keywordPlus | Lithium sulfur batteries | - |
dc.subject.keywordPlus | Lithium-ion batteries | - |
dc.subject.keywordPlus | Sulfur compounds | - |
dc.subject.keywordPlus | Electrochemical kinetics | - |
dc.subject.keywordPlus | Electrolyte lean condition | - |
dc.subject.keywordPlus | Energy density | - |
dc.subject.keywordPlus | Lean condition | - |
dc.subject.keywordPlus | Lithium/sulfur batteries | - |
dc.subject.keywordPlus | Polysulphides | - |
dc.subject.keywordPlus | Power densities | - |
dc.subject.keywordPlus | Practical energies | - |
dc.subject.keywordPlus | Practical energy and power density | - |
dc.subject.keywordPlus | Surface Functionalization | - |
dc.subject.keywordPlus | Graphene | - |
dc.subject.keywordAuthor | electrolyte lean condition | - |
dc.subject.keywordAuthor | graphene | - |
dc.subject.keywordAuthor | lithium& | - |
dc.subject.keywordAuthor | #8208 | - |
dc.subject.keywordAuthor | sulfur batteries | - |
dc.subject.keywordAuthor | practical energy and power density | - |
dc.subject.keywordAuthor | surface functionalization | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/10.1002/smll.202007242 | - |
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