Effect of boron/phosphorus ratio in lithium boron phosphorus oxynitride thin film electrolytes for all-solid-state thin film batteries
DC Field | Value | Language |
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dc.contributor.author | Park, Chanhwi | - |
dc.contributor.author | Lee, Sangsoo | - |
dc.contributor.author | Choi, Sunho | - |
dc.contributor.author | Shin, Dongwook | - |
dc.date.accessioned | 2021-08-02T10:53:42Z | - |
dc.date.available | 2021-08-02T10:53:42Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2019-09 | - |
dc.identifier.issn | 0040-6090 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/12558 | - |
dc.description.abstract | For application to all-solid-state thin film batteries, lithium boron phosphorus oxynitride (LiBPON) thin films were fabricated by RF magnetron sputtering technique of lithium borate (Li₃BO₃) and lithium phosphate (Li₃PO₄) target under N₂ atmosphere. To investigate the mixed former effect upon the LiBPON thin films, we prepared various films with controlled B and P contents. The LiBPON thin film formulation with nearly equal B and P contents showed the highest room-temperature lithium ionic conductivity of 3.52 x 10⁻⁶S cm⁻¹ and the lowest activation energy of 48.24 kJ mol⁻¹ owing to the mixed former effect, the increased lithium content and nitridation. Infrared spectra of the glass thin films achieved two dominant peaks corresponding to BO₃³⁻ and PO₄³⁻ unit. N1s spectra were analyzed by X-ray photoelectron spectroscopy that the increased ionic conductivities observed were related to the formation of triply coordinated nitrogen. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.title | Effect of boron/phosphorus ratio in lithium boron phosphorus oxynitride thin film electrolytes for all-solid-state thin film batteries | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Shin, Dongwook | - |
dc.identifier.doi | 10.1016/j.tsf.2019.06.055 | - |
dc.identifier.scopusid | 2-s2.0-85068674924 | - |
dc.identifier.wosid | 000476884100059 | - |
dc.identifier.bibliographicCitation | THIN SOLID FILMS, v.685, pp.434 - 439 | - |
dc.relation.isPartOf | THIN SOLID FILMS | - |
dc.citation.title | THIN SOLID FILMS | - |
dc.citation.volume | 685 | - |
dc.citation.startPage | 434 | - |
dc.citation.endPage | 439 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Coatings & Films | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | LI | - |
dc.subject.keywordPlus | TRANSPORT | - |
dc.subject.keywordAuthor | Thin film electrolyte | - |
dc.subject.keywordAuthor | Lithium borate | - |
dc.subject.keywordAuthor | Lithium phosphate | - |
dc.subject.keywordAuthor | Lithium boron phosphorus oxynitride | - |
dc.subject.keywordAuthor | All-solid-state batteries | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0040609019304249?via%3Dihub | - |
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