Energy Transfer Photocatalytic Radical Rearrangement in N-Indolyl Carbonates
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Bera, Milan | - |
dc.contributor.author | Hwang, Ho Seong | - |
dc.contributor.author | Um, Tae-Woong | - |
dc.contributor.author | Oh, Soo Min | - |
dc.contributor.author | Shin, Seunghoon | - |
dc.contributor.author | Cho, Eun Jin | - |
dc.date.accessioned | 2022-07-06T08:36:07Z | - |
dc.date.available | 2022-07-06T08:36:07Z | - |
dc.date.created | 2022-04-06 | - |
dc.date.issued | 2022-03 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/139265 | - |
dc.description.abstract | A new type of sp(3)-like N-centered radical has been generated by selective energy transfer catalysis. Upon photoexcitation, homolytic N-O bond cleavage of N-indolyl carbonate in the presence of an Ir complex produced N- and O- centered radicals. The high spin density at the C3 position of indole led to radical recombination with the O-centered radical, affording valuable 3-oxyindole derivatives without decarboxylation. Transformations of the desired products into various molecules were also demonstrated. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Energy Transfer Photocatalytic Radical Rearrangement in N-Indolyl Carbonates | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Shin, Seunghoon | - |
dc.identifier.doi | 10.1021/acs.orglett.2c00085 | - |
dc.identifier.scopusid | 2-s2.0-85126143723 | - |
dc.identifier.wosid | 000770063700004 | - |
dc.identifier.bibliographicCitation | ORGANIC LETTERS, v.24, no.9, pp.1774 - 1779 | - |
dc.relation.isPartOf | ORGANIC LETTERS | - |
dc.citation.title | ORGANIC LETTERS | - |
dc.citation.volume | 24 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 1774 | - |
dc.citation.endPage | 1779 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | TERTIARY AMINE OXIDES | - |
dc.subject.keywordPlus | ACETOXYLATION | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acs.orglett.2c00085 | - |
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