Light-Active, Reversibly Shape-Shifting Block Copolymer Particles Using Photo-switchable Au Nanoparticle Surfactants
DC Field | Value | Language |
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dc.contributor.author | Kwon, Seung Ho | - |
dc.contributor.author | Xu, Meng | - |
dc.contributor.author | Kim, Jinwoo | - |
dc.contributor.author | Kim, Eun Ji | - |
dc.contributor.author | Lee, Young Jun | - |
dc.contributor.author | Jang, Se Gyu | - |
dc.contributor.author | Yun, Hongseok | - |
dc.contributor.author | Kim, Bumjoon J. | - |
dc.date.accessioned | 2022-07-06T11:04:12Z | - |
dc.date.available | 2022-07-06T11:04:12Z | - |
dc.date.created | 2022-01-05 | - |
dc.date.issued | 2021-12 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/140152 | - |
dc.description.abstract | Dynamic particles with switchable shapes in response to light have attracted great interest to develop programmable smart materials with superior spatial and temporal resolution. Herein, a facile strategy for light-responsive, shape-changing block copolymer (BCP) particles is developed. Key to this strategy is the design of azobenzene-grafted Au nanoparticles (Au@ Azo NPs) as photoswitchable surfactants through photoisomerization of Azo ligands. Under visible light, onion-like polystyrene-block-poly(2-vinylpyridine) (PS-b-P2VP) BCP particles with PS outer layer form due to the nonpolar nature of trans-Azo ligands, whereas the isomerization to polar cis-Azo surfactants with UV irradiation transforms these spheres into ellipsoids with both PS and P2VP exposed on their surfaces. This light-driven shape change is robust and reversible over multiple irradiation cycles. The reversible shape evolution between spherical and ellipsoidal BCP particles induced by photoactive Au@Azo NP surfactants is elucidated using a cryogenic electron microscope. Furthermore, light-dependent fluorescence and shape of the BCP particles are successfully demonstrated, enabling the visualization of particle shape into an optical signal. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Light-Active, Reversibly Shape-Shifting Block Copolymer Particles Using Photo-switchable Au Nanoparticle Surfactants | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yun, Hongseok | - |
dc.identifier.doi | 10.1021/acs.chemmater.1c03684 | - |
dc.identifier.scopusid | 2-s2.0-85121107136 | - |
dc.identifier.wosid | 000730589100001 | - |
dc.identifier.bibliographicCitation | CHEMISTRY OF MATERIALS, v.33, no.24, pp.9769 - 9779 | - |
dc.relation.isPartOf | CHEMISTRY OF MATERIALS | - |
dc.citation.title | CHEMISTRY OF MATERIALS | - |
dc.citation.volume | 33 | - |
dc.citation.number | 24 | - |
dc.citation.startPage | 9769 | - |
dc.citation.endPage | 9779 | - |
dc.type.rims | ART | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | GOLD NANOPARTICLES | - |
dc.subject.keywordPlus | FACILE SYNTHESIS | - |
dc.subject.keywordPlus | POLYMER | - |
dc.subject.keywordPlus | ASSEMBLIES | - |
dc.subject.keywordPlus | PHOTOISOMERIZATION | - |
dc.subject.keywordPlus | AGGREGATION | - |
dc.subject.keywordPlus | COMPOSITES | - |
dc.subject.keywordPlus | TRANSITION | - |
dc.subject.keywordPlus | MICELLES | - |
dc.subject.keywordPlus | LOCATION | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acs.chemmater.1c03684 | - |
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