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A Stereodivergent Strategy for Total Syntheses of Antirhine Alkaloids

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dc.contributor.authorPark, Eunjoon-
dc.contributor.authorBae, Cheolwoo-
dc.contributor.authorCho, Cheon-Gyu-
dc.contributor.authorCheon, Cheol-Hong-
dc.date.accessioned2022-07-07T00:31:42Z-
dc.date.available2022-07-07T00:31:42Z-
dc.date.created2021-07-14-
dc.date.issued2021-03-
dc.identifier.issn0022-3263-
dc.identifier.urihttps://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/142205-
dc.description.abstractTotal syntheses of the antirhine alkaloids are described. The cyanide-catalyzed imino-Stetter reaction of the aldimine derived from ethyl 2-aminocinnamate and 4-bromopyridine-2-carboxaldehyde provided a 2-pyridinyl substituted indole-3-acetate, which was further converted into the corresponding indoloquinolizidinium intermediate through C-ring formation. Subsequent trans-selective installation of the homoallylic alcohol side-chain at C-15 in the resulting indoloquinolizidinium allowed the total syntheses of antirhine and its known epimer.-
dc.language영어-
dc.language.isoen-
dc.publisherAMER CHEMICAL SOC-
dc.titleA Stereodivergent Strategy for Total Syntheses of Antirhine Alkaloids-
dc.typeArticle-
dc.contributor.affiliatedAuthorCho, Cheon-Gyu-
dc.identifier.doi10.1021/acs.joc.0c02936-
dc.identifier.scopusid2-s2.0-85103319078-
dc.identifier.wosid000631442900013-
dc.identifier.bibliographicCitationJOURNAL OF ORGANIC CHEMISTRY, v.86, no.6, pp.4497 - 4511-
dc.relation.isPartOfJOURNAL OF ORGANIC CHEMISTRY-
dc.citation.titleJOURNAL OF ORGANIC CHEMISTRY-
dc.citation.volume86-
dc.citation.number6-
dc.citation.startPage4497-
dc.citation.endPage4511-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusINDOLE ALKALOIDS-
dc.identifier.urlhttps://pubs.acs.org/doi/10.1021/acs.joc.0c02936-
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