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Gold-Catalyzed Carbene Transfer Reactions
- Authors
- Shin, Seunghoon
- Issue Date
- Dec-2014
- Publisher
- Springer Verlag
- Keywords
- Carbene transfer; Gold carbene; Gold catalysis; Oxygen atom transfer
- Citation
- Topics in Current Chemistry, v.357, pp 25 - 62
- Pages
- 38
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- Topics in Current Chemistry
- Volume
- 357
- Start Page
- 25
- End Page
- 62
- ISSN
- 0340-1022
1436-5049
- Abstract
- In homogeneous gold catalysis, generations and reactions of metal carbenes have been one of the most rapidly developing areas because of their diverse reactivity under mild conditions. This review covers recent advances in the gold-catalyzed oxygen atom transfer and carbene transfer reactions to alkynes. Atom transfer to an alkyne enables alkynes to function as metal carbene synthons. Many such reactions fulfill redox neutrality starting from safe and easily handled precursors.
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Related Researcher
- Shin, Seung hoon
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)