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Selectivity control by silver catalysts in the cycloisomerization of 1,6-enynes derived from propiolamides
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Koo, Jaeyoung | - |
| dc.contributor.author | Park, Hyun-Sub | - |
| dc.contributor.author | Shin, Seunghoon | - |
| dc.date.accessioned | 2022-07-07T06:50:51Z | - |
| dc.date.available | 2022-07-07T06:50:51Z | - |
| dc.date.issued | 2013-02 | - |
| dc.identifier.issn | 0040-4039 | - |
| dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/143766 | - |
| dc.description.abstract | Silver-catalyzed cycloisomerizations of 1,6-enynes derived from propiolamides led to a selective formation of Alder-ene type 1,4-dienes. Interestingly, AgNTf2 outperformed gold or platinum catalysts in terms of selectivity and reactivity, providing the 1,4-dienes at room temperature. The presence of C(5) carbonyl group in combination with Ag salts is key to the selectivity and the beta-oxo coordinated silver carbenoids were proposed as an intermediate based on the reaction profiles. | - |
| dc.format.extent | 6 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | Elsevier BV | - |
| dc.title | Selectivity control by silver catalysts in the cycloisomerization of 1,6-enynes derived from propiolamides | - |
| dc.type | Article | - |
| dc.publisher.location | 영국 | - |
| dc.identifier.doi | 10.1016/j.tetlet.2012.11.067 | - |
| dc.identifier.scopusid | 2-s2.0-84872289072 | - |
| dc.identifier.wosid | 000314559500023 | - |
| dc.identifier.bibliographicCitation | Tetrahedron Letters, v.54, no.8, pp 834 - 839 | - |
| dc.citation.title | Tetrahedron Letters | - |
| dc.citation.volume | 54 | - |
| dc.citation.number | 8 | - |
| dc.citation.startPage | 834 | - |
| dc.citation.endPage | 839 | - |
| dc.type.docType | Article | - |
| dc.description.isOpenAccess | N | - |
| dc.description.journalRegisteredClass | sci | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.subject.keywordPlus | GOLD(I)-CATALYZED CYCLOISOMERIZATION | - |
| dc.subject.keywordPlus | SKELETAL REARRANGEMENT | - |
| dc.subject.keywordPlus | GOLD(I) CATALYSIS | - |
| dc.subject.keywordPlus | BOND FORMATION | - |
| dc.subject.keywordPlus | ENYNES | - |
| dc.subject.keywordPlus | CYCLOADDITIONS | - |
| dc.subject.keywordPlus | CYCLIZATION | - |
| dc.subject.keywordPlus | 1,N-ENYNES | - |
| dc.subject.keywordPlus | ALLYLSTANNANES | - |
| dc.subject.keywordPlus | ALLYLSILANES | - |
| dc.subject.keywordAuthor | 1,6-Enyne | - |
| dc.subject.keywordAuthor | Cycloisomerization | - |
| dc.subject.keywordAuthor | Silver catalysis | - |
| dc.subject.keywordAuthor | Propiolamide | - |
| dc.subject.keywordAuthor | Silver carbenoid | - |
| dc.subject.keywordAuthor | Gold catalysis | - |
| dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0040403912020217?via%3Dihub | - |
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Related Researcher
- Shin, Seung hoon
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)