Gold(III)-Catalyzed Intramolecular Furanylation and Cyclopropanation of Acyclic Conjugated Enynones
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Oh, Chang Ho | - |
dc.contributor.author | Piao, Lanhua | - |
dc.contributor.author | Kim, Ji Hee | - |
dc.date.accessioned | 2022-07-07T06:54:28Z | - |
dc.date.available | 2022-07-07T06:54:28Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2013-01 | - |
dc.identifier.issn | 0039-7881 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/143777 | - |
dc.description.abstract | We have developed an efficient cascade gold-catalyzed furanylation-cyclopropanation of acyclic (E)-deca-2,9-dien-4-yn-1-ones and an (E)-undeca-2,10-dien-4-yn-1-one to give 1-(2-furyl)bicyclo[3.1.0]hexanes and a 1-(2-furyl) bicyclo[4.1.0]heptane, respectively. This requires a configurational change from the E-isomer to the Z-isomer prior to furan formation. The intermediate was proposed to be a gold-carbene, which would undergo cyclopropanation to furnish the product. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | GEORG THIEME VERLAG KG | - |
dc.title | Gold(III)-Catalyzed Intramolecular Furanylation and Cyclopropanation of Acyclic Conjugated Enynones | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Oh, Chang Ho | - |
dc.identifier.doi | 10.1055/s-0032-1317926 | - |
dc.identifier.scopusid | 2-s2.0-84872173216 | - |
dc.identifier.wosid | 000313362800005 | - |
dc.identifier.bibliographicCitation | SYNTHESIS-STUTTGART, v.45, no.2, pp.174 - 182 | - |
dc.relation.isPartOf | SYNTHESIS-STUTTGART | - |
dc.citation.title | SYNTHESIS-STUTTGART | - |
dc.citation.volume | 45 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 174 | - |
dc.citation.endPage | 182 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | CONTAINING CARBONYL YLIDES | - |
dc.subject.keywordPlus | PLATINUM-CATALYZED CYCLIZATION | - |
dc.subject.keywordPlus | BOUND PYRYLIUM | - |
dc.subject.keywordPlus | CYCLIC ETHERS | - |
dc.subject.keywordPlus | GOLD | - |
dc.subject.keywordPlus | CYCLOISOMERIZATION | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | GENERATION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | INSERTION | - |
dc.subject.keywordAuthor | cyclization | - |
dc.subject.keywordAuthor | gold catalyst | - |
dc.subject.keywordAuthor | furanylation | - |
dc.subject.keywordAuthor | cyclopropanation | - |
dc.subject.keywordAuthor | enynone | - |
dc.identifier.url | https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0032-1317926 | - |
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