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Gold(III)-Catalyzed Intramolecular Furanylation and Cyclopropanation of Acyclic Conjugated Enynones

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dc.contributor.authorOh, Chang Ho-
dc.contributor.authorPiao, Lanhua-
dc.contributor.authorKim, Ji Hee-
dc.date.accessioned2022-07-07T06:54:28Z-
dc.date.available2022-07-07T06:54:28Z-
dc.date.created2021-05-12-
dc.date.issued2013-01-
dc.identifier.issn0039-7881-
dc.identifier.urihttps://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/143777-
dc.description.abstractWe have developed an efficient cascade gold-catalyzed furanylation-cyclopropanation of acyclic (E)-deca-2,9-dien-4-yn-1-ones and an (E)-undeca-2,10-dien-4-yn-1-one to give 1-(2-furyl)bicyclo[3.1.0]hexanes and a 1-(2-furyl) bicyclo[4.1.0]heptane, respectively. This requires a configurational change from the E-isomer to the Z-isomer prior to furan formation. The intermediate was proposed to be a gold-carbene, which would undergo cyclopropanation to furnish the product.-
dc.language영어-
dc.language.isoen-
dc.publisherGEORG THIEME VERLAG KG-
dc.titleGold(III)-Catalyzed Intramolecular Furanylation and Cyclopropanation of Acyclic Conjugated Enynones-
dc.typeArticle-
dc.contributor.affiliatedAuthorOh, Chang Ho-
dc.identifier.doi10.1055/s-0032-1317926-
dc.identifier.scopusid2-s2.0-84872173216-
dc.identifier.wosid000313362800005-
dc.identifier.bibliographicCitationSYNTHESIS-STUTTGART, v.45, no.2, pp.174 - 182-
dc.relation.isPartOfSYNTHESIS-STUTTGART-
dc.citation.titleSYNTHESIS-STUTTGART-
dc.citation.volume45-
dc.citation.number2-
dc.citation.startPage174-
dc.citation.endPage182-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusCONTAINING CARBONYL YLIDES-
dc.subject.keywordPlusPLATINUM-CATALYZED CYCLIZATION-
dc.subject.keywordPlusBOUND PYRYLIUM-
dc.subject.keywordPlusCYCLIC ETHERS-
dc.subject.keywordPlusGOLD-
dc.subject.keywordPlusCYCLOISOMERIZATION-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusGENERATION-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusINSERTION-
dc.subject.keywordAuthorcyclization-
dc.subject.keywordAuthorgold catalyst-
dc.subject.keywordAuthorfuranylation-
dc.subject.keywordAuthorcyclopropanation-
dc.subject.keywordAuthorenynone-
dc.identifier.urlhttps://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0032-1317926-
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