Synthesis of heteroleptic Ru(II) complexes ligated with 1,3-dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one and application in dye-sensitized solar cells
DC Field | Value | Language |
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dc.contributor.author | Tak, Jungae | - |
dc.contributor.author | Oh, Hyunju | - |
dc.contributor.author | Kim, Jungwook | - |
dc.contributor.author | Yun, Soo Hong | - |
dc.contributor.author | Lee, Jihoon | - |
dc.contributor.author | Park, Byoungchoo | - |
dc.contributor.author | Kim, Byeong Hyo | - |
dc.date.accessioned | 2022-07-07T13:33:39Z | - |
dc.date.available | 2022-07-07T13:33:39Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2014-07 | - |
dc.identifier.issn | 0379-6779 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/144609 | - |
dc.description.abstract | Four heteroleptic ruthenium(II) complexes, HJ1-HJ4 [Ru(L)(DTDP)(NCS)2][TBA], (where DTDP = 1, 3-dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[l]phenanthren-2-one, L=4,4'-dicarboxy-2,21-bipyridine (dcbpy, HJ1), 4,4'-bis(E-carboxyviny1)-2,2'-bipyridine (dcvbpy, HJ2), 4,7-dicarboxy-1,10-phenanthroline (dcphen, HJ3), or 4,7-bis(E-carboxyviny1)-1,10-phenanthroline (dcvphen, HJ4)), were synthesized from one-pot reaction of [RuCl2(p-cymene)12 and DTDP ligand followed by addition of the second ligand (L= dcbpy, dcvbpy, dcphen, or dcvphen). Final products were obtained as tetrabutylammonium salt form of ruthenium(II) complexes with reasonable yields. We demonstrated that a dye-sensitized solar cell (DSSC) fabricated with HJ1 dye exhibited a conversion efficiency (77) of 2.8%, which is close to that of standard N719 dye, while other cells fabricated with HJ2-HJ4 dye had conversion efficiencies (n) of between 1.2 and 2.0%. 2014 Elsevier B.V. All rights reserved. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.title | Synthesis of heteroleptic Ru(II) complexes ligated with 1,3-dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one and application in dye-sensitized solar cells | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Tak, Jungae | - |
dc.identifier.doi | 10.1016/j.synthmet.2014.10.029 | - |
dc.identifier.scopusid | 2-s2.0-84908461684 | - |
dc.identifier.wosid | 000346540500039 | - |
dc.identifier.bibliographicCitation | SYNTHETIC METALS, v.145, no.7, pp.1101 - 1108 | - |
dc.relation.isPartOf | SYNTHETIC METALS | - |
dc.citation.title | SYNTHETIC METALS | - |
dc.citation.volume | 145 | - |
dc.citation.number | 7 | - |
dc.citation.startPage | 1101 | - |
dc.citation.endPage | 1108 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.subject.keywordPlus | CHARGE-TRANSFER SENSITIZERS | - |
dc.subject.keywordPlus | RUTHENIUM SENSITIZER | - |
dc.subject.keywordPlus | ELECTRON-DONOR | - |
dc.subject.keywordPlus | THIOPHENE | - |
dc.subject.keywordPlus | SUBSTITUENTS | - |
dc.subject.keywordPlus | LUMINESCENT | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordAuthor | Dye-sensitized solar cells (DSSCs) | - |
dc.subject.keywordAuthor | Ru(II) polypyridyl complexes | - |
dc.subject.keywordAuthor | Phenanthroline | - |
dc.subject.keywordAuthor | Photosensitizer | - |
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