Pd-Catalyzed Sequential C-C Bond Formation and Cleavage: Evidence for an Unexpected Generation of Arylpalladium(II) Species
DC Field | Value | Language |
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dc.contributor.author | Youn, So Won | - |
dc.contributor.author | Kim, Byung Seok | - |
dc.contributor.author | Jagdale, Arun R. | - |
dc.date.accessioned | 2022-07-07T13:53:53Z | - |
dc.date.available | 2022-07-07T13:53:53Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2012-07 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/144754 | - |
dc.description.abstract | A Pd(II)-catalyzed reaction engaging alkenyl beta-keto esters is reported that leads to the formation of 1-naphthols and an unexpected generation of arylpalladium-(II) species. Interception of the in situ generated arylpalladium(II) species in a Mizoroki-Heck reaction, together with additional mechanistic studies, provided strong evidence in support of the first aromatization-driven beta-carbon elimination process. A single Pd catalyst served to promote a series of both C-C bond forming and cleavage events in an unprecedented manner. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Pd-Catalyzed Sequential C-C Bond Formation and Cleavage: Evidence for an Unexpected Generation of Arylpalladium(II) Species | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Youn, So Won | - |
dc.identifier.doi | 10.1021/ja304616q | - |
dc.identifier.scopusid | 2-s2.0-84863901402 | - |
dc.identifier.wosid | 000306457900003 | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.134, no.28, pp.11308 - 11311 | - |
dc.relation.isPartOf | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 134 | - |
dc.citation.number | 28 | - |
dc.citation.startPage | 11308 | - |
dc.citation.endPage | 11311 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | ACTIVATED METHYLENE-COMPOUNDS | - |
dc.subject.keywordPlus | BETA-CARBON ELIMINATION | - |
dc.subject.keywordPlus | MOLECULAR-OXYGEN | - |
dc.subject.keywordPlus | INTRAMOLECULAR ADDITION | - |
dc.subject.keywordPlus | UNACTIVATED OLEFINS | - |
dc.subject.keywordPlus | PALLADIUM | - |
dc.subject.keywordPlus | ALKENES | - |
dc.subject.keywordPlus | HYDROALKYLATION | - |
dc.subject.keywordPlus | CYCLIZATIONS | - |
dc.subject.keywordPlus | ALKYLATION | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ja304616q | - |
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