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beta-Silyl Styrene As a Dienophile in the Cycloaddition with 3,5-Dibromo-2-pyrone for the Total Synthesis of (+/-)-Pancratistatin
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Jung, Yong-Geun | - |
| dc.contributor.author | Kang, Ho-Ung | - |
| dc.contributor.author | Cho, Hyun-Kyu | - |
| dc.contributor.author | Cho, Cheon-Gyu | - |
| dc.date.accessioned | 2022-07-07T14:14:56Z | - |
| dc.date.available | 2022-07-07T14:14:56Z | - |
| dc.date.issued | 2011-11 | - |
| dc.identifier.issn | 1523-7060 | - |
| dc.identifier.issn | 1523-7052 | - |
| dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/144823 | - |
| dc.description.abstract | A new synthetic route to (+/-)-pancratistatin was devised utilizing beta-silyl styrene as a dienophile in the cycloaddition with 3,5-dibromo-2-pyrone. The TMS group incorporated in the cycloadduct permitted a facile elimination process for the eventual installation of the C(1)-OH function. Subsequent transformations including Curtius rearrangement and Bischler-Napieralski reactions completed the total synthesis of (+/-)-pancratistatin. | - |
| dc.format.extent | 3 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | American Chemical Society | - |
| dc.title | beta-Silyl Styrene As a Dienophile in the Cycloaddition with 3,5-Dibromo-2-pyrone for the Total Synthesis of (+/-)-Pancratistatin | - |
| dc.type | Article | - |
| dc.publisher.location | 미국 | - |
| dc.identifier.doi | 10.1021/ol202525a | - |
| dc.identifier.scopusid | 2-s2.0-80055084410 | - |
| dc.identifier.wosid | 000296212200047 | - |
| dc.identifier.bibliographicCitation | Organic Letters, v.13, no.21, pp 5890 - 5892 | - |
| dc.citation.title | Organic Letters | - |
| dc.citation.volume | 13 | - |
| dc.citation.number | 21 | - |
| dc.citation.startPage | 5890 | - |
| dc.citation.endPage | 5892 | - |
| dc.type.docType | Article | - |
| dc.description.isOpenAccess | N | - |
| dc.description.journalRegisteredClass | sci | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.subject.keywordPlus | DIELS-ALDER REACTION | - |
| dc.subject.keywordPlus | ANTINEOPLASTIC AGENTS | - |
| dc.subject.keywordPlus | AMARYLLIDACEAE ALKALOIDS | - |
| dc.subject.keywordPlus | (+)-PANCRATISTATIN | - |
| dc.subject.keywordPlus | PANCRATISTATIN | - |
| dc.subject.keywordPlus | NARCICLASINE | - |
| dc.subject.keywordPlus | (+)-NARCICLASINE | - |
| dc.subject.keywordPlus | (+/-)-CRININE | - |
| dc.identifier.url | https://pubs.acs.org/doi/10.1021/ol202525a | - |
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Related Researcher
- Cho, Cheon Gyu
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)