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Study on the Room-temperature Oxidation of a Fe Thin Film on Pt(110)

Authors
Cho, Seong-GukPark, Kyung HoonHan, Doo-HeunNahm, Tschang Uh
Issue Date
Jul-2011
Publisher
KOREAN PHYSICAL SOC
Keywords
Iron oxides; Iron; Platinum; Oxidation; X-ray photoelectron spectroscopy; XPS
Citation
JOURNAL OF THE KOREAN PHYSICAL SOCIETY, v.59, no.1, pp.105 - 109
Indexed
SCIE
SCOPUS
KCI
Journal Title
JOURNAL OF THE KOREAN PHYSICAL SOCIETY
Volume
59
Number
1
Start Page
105
End Page
109
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/144871
DOI
10.3938/jkps.59.105
ISSN
0374-4884
Abstract
The chemical states of Fe-oxide films deposited on Pt(110) surfaces were investigated by using X-ray photoelectron spectroscopy. The films were prepared by exposing 4- or 6-monolayer (ML) Fe films pre-deposited on the substrates to oxygen. After a 300-Langmuir oxygen exposure at room temperature, the films were observed to be partially oxidized as a mixture of FeO and Fe(3)O(4) phases, and the relative amount of the Fe(3)O(4) phase was larger for the 6-ML Fe film than for the 4-ML film. Upon post-annealing, the oxides decomposed into Fe atoms and desorbing O(2) molecules, and the former interdifFused into the substrate at temperatures higher than 700 K.
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