β-Oxidation of Ynamides into N, O-Acetals by mCPBA: Application in Enantioselective Intermolecular Transacetalization
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Nguyen, Nguyen H. | - |
dc.contributor.author | Nguyen, Quynh H. | - |
dc.contributor.author | Biswas, Soumen | - |
dc.contributor.author | Patil, Dilip V. | - |
dc.contributor.author | Shin, Seunghoon | - |
dc.date.accessioned | 2022-07-09T03:10:03Z | - |
dc.date.available | 2022-07-09T03:10:03Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2019-11 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/146887 | - |
dc.description.abstract | Oxidation of ynamides by mCPBA led to beta-oxygenation and resulted in formation of carbonyl compounds with alpha-N,O-acetal functionality. These N,O-acetals are formed in high yields and can be stored indefinitely at room temperature. Yet, they can be activated by a chiral Bronsted acid and underwent an enantioselective transacetalization into a alpha-N,O-acetal. Subsequent diastereoselective transformations occurred with exceptional selectivity according to Felkin-Anh model. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | β-Oxidation of Ynamides into N, O-Acetals by mCPBA: Application in Enantioselective Intermolecular Transacetalization | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Shin, Seunghoon | - |
dc.identifier.doi | 10.1021/acs.orglett.9b03411 | - |
dc.identifier.scopusid | 2-s2.0-85074706955 | - |
dc.identifier.wosid | 000497259500031 | - |
dc.identifier.bibliographicCitation | ORGANIC LETTERS, v.21, no.22, pp.9009 - 9013 | - |
dc.relation.isPartOf | ORGANIC LETTERS | - |
dc.citation.title | ORGANIC LETTERS | - |
dc.citation.volume | 21 | - |
dc.citation.number | 22 | - |
dc.citation.startPage | 9009 | - |
dc.citation.endPage | 9013 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | FORMAL 3+2 CYCLOADDITION | - |
dc.subject.keywordPlus | GOLD-CATALYZED ADDITION | - |
dc.subject.keywordPlus | SELECTIVE SYNTHESIS | - |
dc.subject.keywordPlus | CARBENES | - |
dc.subject.keywordPlus | ACCESS | - |
dc.subject.keywordPlus | ALKYNES | - |
dc.subject.keywordPlus | OXIRENE | - |
dc.subject.keywordPlus | IMINES | - |
dc.subject.keywordPlus | EPOXIDATIONS | - |
dc.subject.keywordPlus | GENERATION | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acs.orglett.9b03411 | - |
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