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Oxidant-Controlled Divergent Syntheses of Pyrazoles and Pyrroles by Copper(I)-Catalyzed Oxidative Coupling of β-Enamino Esters

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dc.contributor.authorJang, Su San-
dc.contributor.authorChang, Jun Yeong-
dc.contributor.authorKang, Gil Yeong-
dc.contributor.authorYoun, So Won-
dc.date.accessioned2022-07-09T07:33:08Z-
dc.date.available2022-07-09T07:33:08Z-
dc.date.created2021-05-12-
dc.date.issued2019-09-
dc.identifier.issn2193-5807-
dc.identifier.urihttps://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/147176-
dc.description.abstractCopper(I)-catalyzed oxidative annulations of beta-enamino esters with oxidant dependence are disclosed. These reactions offer divergent syntheses of fully substituted pyrazoles and pyrroles from a common enamine substrate through sequential C-C and N-N or C-N bond-forming reactions in the presence of nitriles as reagent or cosolvent. A mechanism involving radical intermediates generated by single-electron transfer (SET) is proposed for both processes.-
dc.language영어-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.titleOxidant-Controlled Divergent Syntheses of Pyrazoles and Pyrroles by Copper(I)-Catalyzed Oxidative Coupling of β-Enamino Esters-
dc.typeArticle-
dc.contributor.affiliatedAuthorYoun, So Won-
dc.identifier.doi10.1002/ajoc.201900351-
dc.identifier.scopusid2-s2.0-85069651334-
dc.identifier.wosid000476339600001-
dc.identifier.bibliographicCitationASIAN JOURNAL OF ORGANIC CHEMISTRY, v.8, no.9, pp.1668 - 1673-
dc.relation.isPartOfASIAN JOURNAL OF ORGANIC CHEMISTRY-
dc.citation.titleASIAN JOURNAL OF ORGANIC CHEMISTRY-
dc.citation.volume8-
dc.citation.number9-
dc.citation.startPage1668-
dc.citation.endPage1673-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusFREE-RADICAL REACTIONS-
dc.subject.keywordPlusC-C BOND-
dc.subject.keywordPlusCONVENIENT SYNTHESIS-
dc.subject.keywordPlusDIRECT ACCESS-
dc.subject.keywordPlusCYCLIZATION-
dc.subject.keywordPlusAMINO-
dc.subject.keywordPlusDIMERIZATION-
dc.subject.keywordPlusREDUCTION-
dc.subject.keywordPlusEFFICIENT-
dc.subject.keywordPlusALKALOIDS-
dc.subject.keywordAuthorannulation-
dc.subject.keywordAuthorbeta-enamino esters-
dc.subject.keywordAuthorcopper-
dc.subject.keywordAuthornitrogen heterocycles-
dc.subject.keywordAuthoroxidation-
dc.identifier.urlhttps://onlinelibrary.wiley.com/doi/10.1002/ajoc.201900351-
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