Copper-1, 3, 5-benzenetricarboxylate framework nanocrystals on polyaniline: Fabrication, characteristics, and electrochemical application for oxygen reduction reaction
DC Field | Value | Language |
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dc.contributor.author | Cho, Keumnam | - |
dc.contributor.author | Shin, Chan-Yong | - |
dc.contributor.author | Leem, Yun Jin | - |
dc.contributor.author | Sung, Myung Mo | - |
dc.contributor.author | Chang, Jinho | - |
dc.contributor.author | Han, Sung-Hwan | - |
dc.date.accessioned | 2022-07-11T14:51:14Z | - |
dc.date.available | 2022-07-11T14:51:14Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2018-08 | - |
dc.identifier.issn | 1572-6657 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/149621 | - |
dc.description.abstract | In this work, we fabricated copper-1, 3, 5-benzenetricarboxylate framework nanocrystals on polyaniline (nano-Cu-BTCs/PANI) composites via a Layer-by-Layer (LbL) method. By increasing the number of LbL cycles, size and amount of the nano-Cu-BTCs in the composites were increased. The composite with more amounts of nano-Cu-BTCs exhibited larger surface areas and more increased electrical resistivity. The composites were investigated as electrocatalysts for oxygen reduction reaction (ORR) in 0.1 M KOH. Among the nano-Cu-BTCs(x wt%)/PANI (x = 8.2, 12, 20, and 37) composites, the composite with 12 wt% of Cu-BTC nanocrystals showed the best electrocatalytic activity for ORR, which would be mainly associated with destabilization of a OH2- intermediate, resulting in a further reduction reaction of the intermediate to OH- in the alkaline solution. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.title | Copper-1, 3, 5-benzenetricarboxylate framework nanocrystals on polyaniline: Fabrication, characteristics, and electrochemical application for oxygen reduction reaction | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Sung, Myung Mo | - |
dc.contributor.affiliatedAuthor | Chang, Jinho | - |
dc.identifier.doi | 10.1016/j.jelechem.2018.06.006 | - |
dc.identifier.scopusid | 2-s2.0-85048266979 | - |
dc.identifier.wosid | 000443664700023 | - |
dc.identifier.bibliographicCitation | JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v.823, pp.176 - 183 | - |
dc.relation.isPartOf | JOURNAL OF ELECTROANALYTICAL CHEMISTRY | - |
dc.citation.title | JOURNAL OF ELECTROANALYTICAL CHEMISTRY | - |
dc.citation.volume | 823 | - |
dc.citation.startPage | 176 | - |
dc.citation.endPage | 183 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Electrochemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Analytical | - |
dc.relation.journalWebOfScienceCategory | Electrochemistry | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | HIGH-YIELD SYNTHESIS | - |
dc.subject.keywordPlus | ELECTRICAL-CONDUCTIVITY | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | STABILITY | - |
dc.subject.keywordPlus | MEDIA | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordAuthor | Metal organic framework | - |
dc.subject.keywordAuthor | Nanocrystal | - |
dc.subject.keywordAuthor | Layer-by-layer deposition | - |
dc.subject.keywordAuthor | Electrocatalysis | - |
dc.subject.keywordAuthor | Oxygen reduction reaction | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S1572665718304211?via%3Dihub | - |
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