Cyclopropane Intermediates from Insertion Reactions of Platinum-Carbenes: A Route to Heterospiranes
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Kiseong | - |
dc.contributor.author | Kim, Soyung | - |
dc.contributor.author | Oh, Chang Ho | - |
dc.date.accessioned | 2022-07-12T12:56:28Z | - |
dc.date.available | 2022-07-12T12:56:28Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2018-02 | - |
dc.identifier.issn | 0936-5214 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/150586 | - |
dc.description.abstract | Heteroaromatic-anchored enynals with a pendent alkene group were successfully cyclized through a Huisgen-type [3+2] cycloaddition to give a tetracyclic Pt-carbene complex that underwent insertion into the C-H bond in the beta-position to give fused cyclopropanes that are otherwise inaccessible. On heating, the cyclopropanes smoothly rearranged to form the corresponding heterospiranes with excellent levels of stereoselectivity and high yields. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | GEORG THIEME VERLAG KG | - |
dc.title | Cyclopropane Intermediates from Insertion Reactions of Platinum-Carbenes: A Route to Heterospiranes | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Oh, Chang Ho | - |
dc.identifier.doi | 10.1055/s-0036-1591489 | - |
dc.identifier.scopusid | 2-s2.0-85041427555 | - |
dc.identifier.wosid | 000423997400022 | - |
dc.identifier.bibliographicCitation | SYNLETT, v.29, no.3, pp.354 - 358 | - |
dc.relation.isPartOf | SYNLETT | - |
dc.citation.title | SYNLETT | - |
dc.citation.volume | 29 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 354 | - |
dc.citation.endPage | 358 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | CATALYZED SEQUENTIAL ACTIVATION | - |
dc.subject.keywordPlus | 3+2 CYCLIZATION | - |
dc.subject.keywordPlus | BOUND PYRYLIUM | - |
dc.subject.keywordPlus | GOLD | - |
dc.subject.keywordPlus | CYCLOADDITION | - |
dc.subject.keywordPlus | CONSTRUCTION | - |
dc.subject.keywordPlus | ACETATES | - |
dc.subject.keywordPlus | SPIROCYCLES | - |
dc.subject.keywordAuthor | cyclization | - |
dc.subject.keywordAuthor | platinum catalysis | - |
dc.subject.keywordAuthor | pyrylium ions | - |
dc.subject.keywordAuthor | carbenes | - |
dc.subject.keywordAuthor | heterospiranes | - |
dc.identifier.url | https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0036-1591489 | - |
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