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A new small molecule acceptor based on indaceno[2,1-b:6,5-b'] dithiophene and thiophene-fused ending group for fullerene-free organic solar cells

Authors
Xie, DongjunLiu, TaoLee, Tack HoGao, WeiZhong, ChengHuo, LijunLuo, ZhenghuiWu, KailongXiong, WentaoKim, Jin YoungChoi, HyosungSun, YanmingYang, Chuluo
Issue Date
Jan-2018
Publisher
Elsevier BV
Keywords
Non-fullerene acceptors; Small molecule acceptor; End-capping group
Citation
Dyes and Pigments, v.148, pp 263 - 269
Pages
7
Indexed
SCI
SCIE
SCOPUS
Journal Title
Dyes and Pigments
Volume
148
Start Page
263
End Page
269
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/150702
DOI
10.1016/j.dyepig.2017.09.009
ISSN
0143-7208
1873-3743
Abstract
A new small molecule acceptor of IDTCN with indaceno[2,1-b:6,5-b’]dithiophene as electron-donating core and CPTCN (2-(6-oxo-5,6-dihydro-4H-cyclopenta[c]thiophen-4-lidene)malononitrile) as electron-withdrawing end-capping group was synthesized and investigated in organic solar cells. The IDTCN shows strong and broad absorption with a high extinction coefficient and appropriate energy levels matching with wide bandgap donor polymer. The best device based on PBT1-EH:IDTCN exhibits an open circuit voltage (Voc) of 0.93 V, a short circuit current (Jsc) of 13.31 mA/cm2, a FF of 0.702, achieving a PCE of 8.69%.
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