Dinuclear Ru(II) complexes bridged with 5-(2-[2,2 '-bipyridin]-5-ylethynyl)-2,2 '-bipyridine ligand and ligated to ancillary alpha-diimine ligand: synthesis and application to dye-sensitized solar cells
DC Field | Value | Language |
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dc.contributor.author | Choi, Yong Rack | - |
dc.contributor.author | Lee, Woojin | - |
dc.contributor.author | Yun, Soo Hong | - |
dc.contributor.author | Lee, Hyunseung | - |
dc.contributor.author | Tak, Jungae | - |
dc.contributor.author | Park, Byoungchoo | - |
dc.contributor.author | Kim, Byeong Hyo | - |
dc.date.accessioned | 2022-07-12T20:18:12Z | - |
dc.date.available | 2022-07-12T20:18:12Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2017-12 | - |
dc.identifier.issn | 0026-9247 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/151051 | - |
dc.description.abstract | Four heteroleptic dinuclear ruthenium(II) complexes bridged with 5-(2-[2,2'-bipyridin]-5-ylethynyl)-2,2'-bipyridine (bpy-ac-bpy) ligand were prepared and ligated to four different alpha-diimine ligands, [TBA](2)[Ru-2(L)(2)(BL)(NCS)(4)] [where L = 4,4'-dicarboxy-2,2'-bipyridine (dcbpy), 4,4'-bis(E-carboxyvinyl)-2,2'-bipyridine (dcvbpy), 4,7-dicarboxy-1,10-phenanthroline (dcphen), or 4,7-bis(E-carboxyvinyl)-1,10-phenanthroline (dcvphen), BL = bridging ligand]. Their physical and photovoltaic properties were investigated. Among the dye-sensitized solar cells (DSSCs) fabricated with the newly prepared four heteroleptic dinuclear ruthenium(II) complexes, a DSSC fabricated with the heteroleptic dinuclear ruthenium(II) complexes bridged with bpy-ac-bpy and ligated to dcvphen exhibited a reasonable power conversion efficiency (eta) of 2.33%, which is close to that of the N719-sensitized solar cell (3.44%) under the same cell fabrication and measuring conditions. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | SPRINGER WIEN | - |
dc.title | Dinuclear Ru(II) complexes bridged with 5-(2-[2,2 '-bipyridin]-5-ylethynyl)-2,2 '-bipyridine ligand and ligated to ancillary alpha-diimine ligand: synthesis and application to dye-sensitized solar cells | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Tak, Jungae | - |
dc.identifier.doi | 10.1007/s00706-017-2027-4 | - |
dc.identifier.scopusid | 2-s2.0-85029579895 | - |
dc.identifier.wosid | 000415301700004 | - |
dc.identifier.bibliographicCitation | MONATSHEFTE FUR CHEMIE, v.148, no.12, pp.2051 - 2059 | - |
dc.relation.isPartOf | MONATSHEFTE FUR CHEMIE | - |
dc.citation.title | MONATSHEFTE FUR CHEMIE | - |
dc.citation.volume | 148 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 2051 | - |
dc.citation.endPage | 2059 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | CHARGE-TRANSFER SENSITIZERS | - |
dc.subject.keywordPlus | TRANSITION-METAL-COMPLEXES | - |
dc.subject.keywordPlus | NANOCRYSTALLINE TIO2 | - |
dc.subject.keywordPlus | RUTHENIUM SENSITIZER | - |
dc.subject.keywordPlus | PHOTOPHYSICAL PROPERTIES | - |
dc.subject.keywordPlus | POLYPYRIDYL COMPLEXES | - |
dc.subject.keywordPlus | ELECTRON-DONOR | - |
dc.subject.keywordPlus | THIOPHENE | - |
dc.subject.keywordPlus | LIGHT | - |
dc.subject.keywordPlus | SUBSTITUENTS | - |
dc.subject.keywordAuthor | Dye-sensitized solar cells (DSSCs) | - |
dc.subject.keywordAuthor | Organometallic compounds | - |
dc.subject.keywordAuthor | Dinuclear ruthenium(II) complexes | - |
dc.subject.keywordAuthor | Photosensitizers | - |
dc.identifier.url | https://link.springer.com/article/10.1007%2Fs00706-017-2027-4 | - |
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