Crosslinked anion exchange membranes with primary diamine-based crosslinkers for vanadium redox flow battery application
DC Field | Value | Language |
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dc.contributor.author | Cha, Min Suc | - |
dc.contributor.author | Jeong, Hwan Yeop | - |
dc.contributor.author | Shin, Hee Young | - |
dc.contributor.author | Hong, Soo Hyun | - |
dc.contributor.author | Kim, Tae-Ho | - |
dc.contributor.author | Oh, Seong-Geun | - |
dc.contributor.author | Lee, Jang Yong | - |
dc.contributor.author | Hong, Young Taik | - |
dc.date.accessioned | 2022-07-13T15:58:40Z | - |
dc.date.available | 2022-07-13T15:58:40Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2017-09 | - |
dc.identifier.issn | 0378-7753 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/151758 | - |
dc.description.abstract | A series of polysulfone-based crosslinked anion exchange membranes (AEMs) with primary diaminebased crosslinkers has been prepared via simple a crosslinking process as low-cost and durable membranes for vanadium redox flow batteries (VRFBs). Chloromethylated polysulfone is used as a precursor polymer for crosslinked AEM5 (CAPSU-x) with different degrees of crosslinking. Among the deVeloped AEM5, CAPSU-2.5 shows outstanding dimensional stability and anion (Cl-, SO42-, and OH-) conductivity. Moreover, CAPSU-2.5 exhibits much lower vanadium ion permeability (2.72 x 10(-8) cm(2) min(-1)) than Nafion 115 (2.88 x 10(-6) cm(2) min(-1)), which results in an excellent coulombic efficiency of 100%. The chemical and operational stabilities of the membranes have been investigated via ex situ soaking tests in 0.1 M VO2+ solution and in situ operation tests for 100 cycles, respectively. The excellent chemical, physical, and electrochemical properties of the CAPSU-2.5 membrane make it suitable for use in VRFBs. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.title | Crosslinked anion exchange membranes with primary diamine-based crosslinkers for vanadium redox flow battery application | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Oh, Seong-Geun | - |
dc.identifier.doi | 10.1016/j.jpowsour.2017.07.068 | - |
dc.identifier.scopusid | 2-s2.0-85025451975 | - |
dc.identifier.wosid | 000411544300011 | - |
dc.identifier.bibliographicCitation | JOURNAL OF POWER SOURCES, v.363, pp.78 - 86 | - |
dc.relation.isPartOf | JOURNAL OF POWER SOURCES | - |
dc.citation.title | JOURNAL OF POWER SOURCES | - |
dc.citation.volume | 363 | - |
dc.citation.startPage | 78 | - |
dc.citation.endPage | 86 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Electrochemistry | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Electrochemistry | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | ALKALINE FUEL-CELLS | - |
dc.subject.keywordPlus | ELECTROCHEMICAL APPLICATIONS | - |
dc.subject.keywordPlus | BLOCK | - |
dc.subject.keywordPlus | IONOMERS | - |
dc.subject.keywordPlus | LINKING | - |
dc.subject.keywordPlus | CONDUCTIVITY | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | MOIETIES | - |
dc.subject.keywordAuthor | Anion exchange membrane | - |
dc.subject.keywordAuthor | Primary amine crosslinker | - |
dc.subject.keywordAuthor | Redox flow battery | - |
dc.subject.keywordAuthor | Vanadium | - |
dc.subject.keywordAuthor | poly(sulfone)s | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0378775317309606?via%3Dihub | - |
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