Structural and Mechanistic Revision for Gold-catalyzed Sequential Activation of Propargylic Carboxylates
DC Field | Value | Language |
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dc.contributor.author | Kim, Kiseong | - |
dc.contributor.author | Jung, Jaemun | - |
dc.contributor.author | Heo, Hoon Gu | - |
dc.contributor.author | Oh, Chang Ho | - |
dc.date.accessioned | 2022-07-13T16:22:40Z | - |
dc.date.available | 2022-07-13T16:22:40Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2017-08 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/151880 | - |
dc.description.abstract | The structure analysis explains that the gold-catalyzed reaction forms one benzene ring possessing an acetoxyethenyl and an acetoxy groups in 2 and 4 positions. Based on the X-ray analysis, we revised structures of all products reported previously in two papers. The proposed mechanism of this sequence is being revised with an evidence of gold-carbene intermediacy. The proposed gold-carbene intermediate was supported by the control experiment for enyne metathesis route. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Structural and Mechanistic Revision for Gold-catalyzed Sequential Activation of Propargylic Carboxylates | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Oh, Chang Ho | - |
dc.identifier.doi | 10.1002/bkcs.11179 | - |
dc.identifier.scopusid | 2-s2.0-85023617569 | - |
dc.identifier.wosid | 000409036500004 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.38, no.8, pp.845 - 849 | - |
dc.relation.isPartOf | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 38 | - |
dc.citation.number | 8 | - |
dc.citation.startPage | 845 | - |
dc.citation.endPage | 849 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART002249757 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | PLATINUM-BOUND PYRYLIUM | - |
dc.subject.keywordPlus | VINYLIDENE COMPLEXES | - |
dc.subject.keywordPlus | TERMINAL ALKYNES | - |
dc.subject.keywordPlus | 3+2 CYCLIZATION | - |
dc.subject.keywordPlus | CARBENE | - |
dc.subject.keywordPlus | FACILE | - |
dc.subject.keywordPlus | BOND | - |
dc.subject.keywordPlus | SELECTIVITY | - |
dc.subject.keywordPlus | GENERATION | - |
dc.subject.keywordPlus | ACETATES | - |
dc.subject.keywordAuthor | Gold catalysis | - |
dc.subject.keywordAuthor | Propargyl carboxylate | - |
dc.subject.keywordAuthor | Cyclization | - |
dc.subject.keywordAuthor | Gold carbene | - |
dc.subject.keywordAuthor | Enyne metathesis | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/10.1002/bkcs.11179 | - |
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