Bronsted Acid Catalyzed Oxygenative Bimolecular Friedel-Crafts-type Coupling of Ynamides
DC Field | Value | Language |
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dc.contributor.author | Patil, Dilip V. | - |
dc.contributor.author | Kim, Seung Woo | - |
dc.contributor.author | Nguyen, Quynh H. | - |
dc.contributor.author | Kim, Hanbyul | - |
dc.contributor.author | Wang, Shan | - |
dc.contributor.author | Hoang, Tuan | - |
dc.contributor.author | Shin, Seunghoon | - |
dc.date.accessioned | 2022-07-14T15:07:37Z | - |
dc.date.available | 2022-07-14T15:07:37Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2017-03 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/152835 | - |
dc.description.abstract | A non-metal approach for accessing alpha-oxo carbene surrogates for a C-C bond-forming bimolecular coupling between ynamides and nucleophilic arenes was developed. This acid-catalyzed coupling features mild temperature, which is critical for the required temporal chemoselectivity among nucleophiles. The scope of nucleophiles includes indoles, pyrroles, anilines, phenols and silyl enolethers. Furthermore, a direct test of S(N)2' mechanism has been provided by employing chiral N,N'-dioxides which also enlightens the nature of the intermediates in related metal-catalyzed processes. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Bronsted Acid Catalyzed Oxygenative Bimolecular Friedel-Crafts-type Coupling of Ynamides | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Shin, Seunghoon | - |
dc.identifier.doi | 10.1002/anie.201612471 | - |
dc.identifier.scopusid | 2-s2.0-85013635533 | - |
dc.identifier.wosid | 000397339400042 | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.13, pp.3670 - 3674 | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 56 | - |
dc.citation.number | 13 | - |
dc.citation.startPage | 3670 | - |
dc.citation.endPage | 3674 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | OXO GOLD CARBENES | - |
dc.subject.keywordPlus | STEREOSELECTIVE CIS-HYDROARYLATION | - |
dc.subject.keywordPlus | OXIDATIVE CYCLIZATION | - |
dc.subject.keywordPlus | ALKYNES | - |
dc.subject.keywordPlus | CASCADE | - |
dc.subject.keywordPlus | CYCLOADDITION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | CYCLOPROPANATION | - |
dc.subject.keywordAuthor | Bronsted acid catalysis | - |
dc.subject.keywordAuthor | intermolecular trapping | - |
dc.subject.keywordAuthor | pyridine-N-oxides | - |
dc.subject.keywordAuthor | ynamides | - |
dc.subject.keywordAuthor | alpha-oxo carbene surrogate | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/10.1002/anie.201612471 | - |
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