Metal-Free One-Pot Synthesis of N,N '-Diarylamidines and N-Arylbenzimidazoles from Arenediazonium Salts, Nitriles, and Free Anilines
- Authors
- Youn, So Won; Lee, Eun Mi
- Issue Date
- Nov-2016
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v.18, no.21, pp.5728 - 5731
- Indexed
- SCIE
SCOPUS
- Journal Title
- ORGANIC LETTERS
- Volume
- 18
- Number
- 21
- Start Page
- 5728
- End Page
- 5731
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/153647
- DOI
- 10.1021/acs.orglett.6b02994
- ISSN
- 1523-7060
- Abstract
- A highly efficient and facile metal-free, one-pot reaction has been developed to afford diversely substituted N-arylbenzimidazoles through chemoselective in situ generation of N,N'-diarylamidines from arenediazonium salts, nitrites, and free anilines. The advantages of this protocol consist of the operationally easy and simple one-pot procedure under metal-free and mild conditions, the direct use of inexpensive and commercially available chemicals, and thus, a cost-effective and greener process.
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