In-Water and Neat Batch and Continuous-Flow Direct Esterification and Transesterification by a Porous Polymeric Acid Catalyst
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Baek, Heeyoel | - |
dc.contributor.author | Minakawa, Maki | - |
dc.contributor.author | Yamada, Yoichi M. A. | - |
dc.contributor.author | Han, Jin Wook | - |
dc.contributor.author | Uozumi, Yasuhiro | - |
dc.date.accessioned | 2022-07-15T17:30:16Z | - |
dc.date.available | 2022-07-15T17:30:16Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2016-05 | - |
dc.identifier.issn | 2045-2322 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/154704 | - |
dc.description.abstract | A porous phenolsulphonic acid-formaldehyde resin (PAFR) was developed. The heterogeneous catalyst PAFR was applied to the esterification of carboxylic acids and alcohols, affording the carboxylic acid esters in a yield of up to 95% where water was not removed from the reaction mixture. Surprisingly, the esterification in water as a solvent proceeded to afford the desired esters in high yield. PAFR provided the corresponding esters in higher yield than other homogeneous and heterogeneous catalysts. The transesterification of alcohols and esters was also investigated by using PAFR, giving the corresponding esters. PAFR was applied to the batch-wise and continuous-flow production of biodiesel fuel FAME. The PAFR-packed flow reactor that was developed for the synthesis of carboxylic acids and FAME worked for four days without loss of its catalytic activity. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | NATURE RESEARCH | - |
dc.title | In-Water and Neat Batch and Continuous-Flow Direct Esterification and Transesterification by a Porous Polymeric Acid Catalyst | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Han, Jin Wook | - |
dc.identifier.doi | 10.1038/srep25925 | - |
dc.identifier.scopusid | 2-s2.0-84969944932 | - |
dc.identifier.wosid | 000375984400001 | - |
dc.identifier.bibliographicCitation | SCIENTIFIC REPORTS, v.6, pp.1 - 9 | - |
dc.relation.isPartOf | SCIENTIFIC REPORTS | - |
dc.citation.title | SCIENTIFIC REPORTS | - |
dc.citation.volume | 6 | - |
dc.citation.startPage | 1 | - |
dc.citation.endPage | 9 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | Y | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalWebOfScienceCategory | Multidisciplinary Sciences | - |
dc.subject.keywordPlus | CARBOXYLIC-ACIDS | - |
dc.subject.keywordPlus | DEHYDRATION REACTIONS | - |
dc.subject.keywordPlus | ESTER CONDENSATION | - |
dc.subject.keywordPlus | EQUIMOLAR AMOUNTS | - |
dc.subject.keywordPlus | SULFONIC-ACIDS | - |
dc.subject.keywordPlus | ALCOHOLS | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | TOLERANT | - |
dc.subject.keywordPlus | MILD | - |
dc.subject.keywordPlus | ACETYLATION | - |
dc.identifier.url | https://www.nature.com/articles/srep25925 | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
222, Wangsimni-ro, Seongdong-gu, Seoul, 04763, Korea+82-2-2220-1365
COPYRIGHT © 2021 HANYANG UNIVERSITY.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.