The H2 Pressure Dependence of Hydrodeoxygenation Selectivities for Furfural Over Pt/C Catalysts
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Luo, Jing | - |
dc.contributor.author | Monai, Matteo | - |
dc.contributor.author | Yun, Hongseok | - |
dc.contributor.author | Arroyo-Ramirez, Lisandra | - |
dc.contributor.author | Wang, Cong | - |
dc.contributor.author | Murray, Christopher B. | - |
dc.contributor.author | Fornasiero, Paolo | - |
dc.contributor.author | Gorte, Raymond J. | - |
dc.date.accessioned | 2022-07-15T17:50:00Z | - |
dc.date.available | 2022-07-15T17:50:00Z | - |
dc.date.created | 2021-05-14 | - |
dc.date.issued | 2016-04 | - |
dc.identifier.issn | 1011-372X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/154803 | - |
dc.description.abstract | Hydrodeoxygenation of furfural was studied over a 10-wt% Pt/C catalyst at 453 K, under both low- and high-pressure conditions. With vapor-phase furfural as the feed and H-2 pressures below 1 bar, decarbonylation to furan is a major product, with the selectivity to furfuryl alcohol and dimethylfuran increasing with increasing H-2 pressure. When the reaction is performed at 33 bar, using 1-wt % furfural in 1-propanol solvent and high-pressure H-2, no evidence for decarbonylation was observed. At high pressures, the reaction is sequential, with all the furfural proceeding to methylfuran, which in turn reacts to over-hydrogenated products, including 2-methyltetrahydrofuran and 2-pentanone. It is suggested that the hydrogen surface coverage is responsible for the apparent differences in the reaction network at high and low pressures. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | SPRINGER | - |
dc.title | The H2 Pressure Dependence of Hydrodeoxygenation Selectivities for Furfural Over Pt/C Catalysts | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yun, Hongseok | - |
dc.identifier.doi | 10.1007/s10562-016-1705-x | - |
dc.identifier.scopusid | 2-s2.0-84960414586 | - |
dc.identifier.wosid | 000372267200001 | - |
dc.identifier.bibliographicCitation | CATALYSIS LETTERS, v.146, no.4, pp.711 - 717 | - |
dc.relation.isPartOf | CATALYSIS LETTERS | - |
dc.citation.title | CATALYSIS LETTERS | - |
dc.citation.volume | 146 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 711 | - |
dc.citation.endPage | 717 | - |
dc.type.rims | ART | - |
dc.type.docType | 정기학술지(Article(Perspective Article포함)) | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.subject.keywordPlus | CONTINUOUS-FLOW REACTOR | - |
dc.subject.keywordPlus | REACTION PATHWAYS | - |
dc.subject.keywordPlus | BIO-OIL | - |
dc.subject.keywordPlus | HYDROGENATION | - |
dc.subject.keywordPlus | 2,5-DIMETHYLFURAN | - |
dc.subject.keywordPlus | HMF | - |
dc.subject.keywordPlus | TRANSFORMATION | - |
dc.subject.keywordPlus | PYROLYSIS | - |
dc.subject.keywordAuthor | Furfural | - |
dc.subject.keywordAuthor | Hydrodeoxygenation | - |
dc.subject.keywordAuthor | Decarbonylation | - |
dc.subject.keywordAuthor | Continuous flow reactor | - |
dc.subject.keywordAuthor | H-2 pressure dependence | - |
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