Coordination Assembly of Discoid Nanoparticles
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hirai, Kenji | - |
dc.contributor.author | Yeom, Bong jun | - |
dc.contributor.author | Chang, Shu-Hao | - |
dc.contributor.author | Chi, Hang | - |
dc.contributor.author | Mansfield, John F. | - |
dc.contributor.author | Lee, Byeongdu | - |
dc.contributor.author | Lee, Sungsik | - |
dc.contributor.author | Uher, Ctirad | - |
dc.contributor.author | Kotov, Nicholas A. | - |
dc.date.accessioned | 2022-07-15T21:54:59Z | - |
dc.date.available | 2022-07-15T21:54:59Z | - |
dc.date.created | 2021-05-13 | - |
dc.date.issued | 2015-07 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/156757 | - |
dc.description.abstract | Supramolecular chemistry utilizes coordination bonds to assemble molecular building blocks into a variety of sophisticated constructs. However, traditional coordination assemblies are based on organic compounds that have limited ability to transport charge. Herein, we describe coordination assembly of anisotropic FeS2 pyrite nanoparticles (NPs) that can facilitate charge transport. Zn2+ ions form supramolecular complexes with carboxylate end-groups on NP surface, leading to multiparticle sheets with liquid-crystal-like organization. Conductivity and Hall carrier mobility of the p-type layered semiconductor films with Zn2+ coordination bridging exceed those known for coordination compounds, some by several orders of magnitude. The nanoscale porosity of the assembled sheets combined with fast hole transport leads to high electrocatalytic activity of the NP films. The coordination assembly of NPs embraces the versatility of several types of building blocks and opens a new design space for self-organized materials combining nanoscale and supramolecular structural motifs. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Coordination Assembly of Discoid Nanoparticles | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yeom, Bong jun | - |
dc.identifier.doi | 10.1002/anie.201502057 | - |
dc.identifier.scopusid | 2-s2.0-84937735099 | - |
dc.identifier.wosid | 000358501500013 | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.54, no.31, pp.8966 - 8970 | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 54 | - |
dc.citation.number | 31 | - |
dc.citation.startPage | 8966 | - |
dc.citation.endPage | 8970 | - |
dc.type.rims | ART | - |
dc.type.docType | 정기 학술지(Review) | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | Y | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | NANOCRYSTALS | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | ORGANIZATION | - |
dc.subject.keywordPlus | FRAMEWORKS | - |
dc.subject.keywordAuthor | conductive materials | - |
dc.subject.keywordAuthor | coordination bond | - |
dc.subject.keywordAuthor | nanoparticles | - |
dc.subject.keywordAuthor | supramolecular assemblies | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/10.1002/anie.201502057 | - |
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