Application of Rod-Like Li6PS5Cl Directly Synthesized by a Liquid Phase Process to Sheet-Type Electrodes for All-Solid-State Lithium Batteries
DC Field | Value | Language |
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dc.contributor.author | Choi, Sunho | - |
dc.contributor.author | Ann, Jiu | - |
dc.contributor.author | Do, Jiyae | - |
dc.contributor.author | Lim, Seungwoo | - |
dc.contributor.author | Park, Chanhwi | - |
dc.contributor.author | Shin, Dongwook | - |
dc.date.accessioned | 2021-08-02T12:50:55Z | - |
dc.date.available | 2021-08-02T12:50:55Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2018-12 | - |
dc.identifier.issn | 0013-4651 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/15866 | - |
dc.description.abstract | All-solid-state lithium batteries employing sulfide-based solid electrolytes have emerged as promising next-generation batteries for large-scale energy storage applications because of their safety and high energy density. Among them, Li6PS5X (X = Cl, Br, I) with an argyrodite structure synthesized by planetary milling exhibits a rather high lithium ion conductivity of 10(-2)-10(-3) S cm(-1) at room temperature. Unfortunately, the planetary milling process has the disadvantage of producing the solid electrolytes with large, round-shaped particles. Recently, the solid electrolytes have been synthesized by not the mechanical milling but the liquid-phase process, which facilitates synthesis of sub-micrometer-to nanometer-sized solid electrolyte particles. It is important to reduce the particle size of the solid electrolyte to promote intimate contact with the active material in the composite cathode. Here, rod-like Li6PS5Cl solid electrolyte with a high ionic conductivity of 1.1 x 10(-3) S cm(-1) at room temperature was, for the first time, directly prepared by a liquid phase process using only a stirring method. SEM images showed the electrolyte had a rod-like morphology with a length of 20-30 mu m and a width of 2-3 mu m. The composite cathode was prepared from a slurry and the cell performances were investigated. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ELECTROCHEMICAL SOC INC | - |
dc.title | Application of Rod-Like Li6PS5Cl Directly Synthesized by a Liquid Phase Process to Sheet-Type Electrodes for All-Solid-State Lithium Batteries | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Shin, Dongwook | - |
dc.identifier.doi | 10.1149/2.0301903jes | - |
dc.identifier.scopusid | 2-s2.0-85063081123 | - |
dc.identifier.wosid | 000454054300002 | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.166, no.3, pp.A5193 - A5200 | - |
dc.relation.isPartOf | JOURNAL OF THE ELECTROCHEMICAL SOCIETY | - |
dc.citation.title | JOURNAL OF THE ELECTROCHEMICAL SOCIETY | - |
dc.citation.volume | 166 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | A5193 | - |
dc.citation.endPage | A5200 | - |
dc.type.rims | ART | - |
dc.type.docType | Article; Proceedings Paper | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | Y | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Electrochemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Electrochemistry | - |
dc.relation.journalWebOfScienceCategory | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Coatings & Films | - |
dc.subject.keywordPlus | SUPERIONIC CONDUCTOR | - |
dc.subject.keywordPlus | SECONDARY BATTERIES | - |
dc.subject.keywordPlus | LICOO2 ELECTRODE | - |
dc.subject.keywordPlus | FACILE SYNTHESIS | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | MORPHOLOGY | - |
dc.subject.keywordPlus | PARTICLES | - |
dc.identifier.url | https://iopscience.iop.org/article/10.1149/2.0301903jes | - |
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