Ruthenium-Na2CO3-catalyzed one-pot synthesis of ring-hydrogenated carbamates from aromatic amines and organic carbonates under H-2
DC Field | Value | Language |
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dc.contributor.author | Mishra, Vivek | - |
dc.contributor.author | Cho, Jin Ku | - |
dc.contributor.author | Shin, Seung-Han | - |
dc.contributor.author | Suh, Young-Woong | - |
dc.contributor.author | Kim, Hoon Sik | - |
dc.contributor.author | Kim, Yong Jin | - |
dc.date.accessioned | 2022-07-16T02:43:42Z | - |
dc.date.available | 2022-07-16T02:43:42Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2014-10 | - |
dc.identifier.issn | 0926-860X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/159005 | - |
dc.description.abstract | A facile and efficient one-pot procedure for the synthesis of ring hydrogenated carbamates from aromatic amine and alkylene carbonate under H-2 gas pressure has been developed using a heterogeneous catalyst system comprising ruthenium and alkali metal carbonates. The effects of temperature, H-2 pressure, catalyst (types of loaded metal and their supports), molar ratio of substrate/catalyst, and solvent were also investigated. Among the alkali metal carbonates, the sodium carbonate was found as best promoter for nucleophilic attack and ring-opening (NARO) reaction and thus increased the yield of ring hydrogenated carbamate up to 88% when using Ru/C as ring hydrogenation (RH) catalyst. This catalyst system could be reused at least five times without significant loss of activity, which makes this process cost-effective and eco-friendly. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.title | Ruthenium-Na2CO3-catalyzed one-pot synthesis of ring-hydrogenated carbamates from aromatic amines and organic carbonates under H-2 | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Suh, Young-Woong | - |
dc.identifier.doi | 10.1016/j.apcata.2014.09.013 | - |
dc.identifier.scopusid | 2-s2.0-85041788399 | - |
dc.identifier.wosid | 000345479000009 | - |
dc.identifier.bibliographicCitation | APPLIED CATALYSIS A-GENERAL, v.487, pp.82 - 90 | - |
dc.relation.isPartOf | APPLIED CATALYSIS A-GENERAL | - |
dc.citation.title | APPLIED CATALYSIS A-GENERAL | - |
dc.citation.volume | 487 | - |
dc.citation.startPage | 82 | - |
dc.citation.endPage | 90 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Environmental Sciences & Ecology | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Environmental Sciences | - |
dc.subject.keywordPlus | OXIDATIVE CARBONYLATION | - |
dc.subject.keywordPlus | ALKYLENE CARBONATES | - |
dc.subject.keywordPlus | CATALYST | - |
dc.subject.keywordPlus | CYCLOHEXYLAMINE | - |
dc.subject.keywordPlus | ISOCYANATES | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | PHOSGENE | - |
dc.subject.keywordPlus | ANILINE | - |
dc.subject.keywordPlus | SYSTEM | - |
dc.subject.keywordPlus | UREAS | - |
dc.subject.keywordAuthor | Aromatic amine | - |
dc.subject.keywordAuthor | Alkylene carbonate | - |
dc.subject.keywordAuthor | Carbamate | - |
dc.subject.keywordAuthor | Ring hydrogenation | - |
dc.subject.keywordAuthor | Ruthenium catalyst | - |
dc.subject.keywordAuthor | Sodium carbonate | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0926860X14005638?via%3Dihub | - |
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