Chiral Plasmonic Nanostructures on Achiral Nanopillars
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yeom, Bongjun | - |
dc.contributor.author | Zhang, Huanan | - |
dc.contributor.author | Zhang, Hui | - |
dc.contributor.author | Park, Jai Il | - |
dc.contributor.author | Kim, Kyoungwon | - |
dc.contributor.author | Govorov, Alexander O. | - |
dc.contributor.author | Kotov, Nicholas A. | - |
dc.date.accessioned | 2022-07-16T07:27:17Z | - |
dc.date.available | 2022-07-16T07:27:17Z | - |
dc.date.created | 2021-05-13 | - |
dc.date.issued | 2013-11 | - |
dc.identifier.issn | 1530-6984 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/161446 | - |
dc.description.abstract | Chirality of plasmonic films can be strongly enhanced by three-dimensional (3D) out-of-plane geometries. The complexity of lithographic methods currently used to produce such structures and other methods utilizing chiral templates impose limitations on spectral windows of chiroptical effects, the size of substrates, and hence, further research on chiral plasmonics. Here we demonstrate 3D chiral plasmonic nanostructures (CPNs) with high optical activity in the visible spectral range based on initially achiral nanopillars from ZnO. We made asymmetric gold nanoshells on the nanopillars by vacuum evaporation at different inclination and rotation angles to achieve controlled symmetry breaking and obtained both left- and right-rotating isomers. The attribution of chiral optical effects to monolithic enantiomers made in this process was confirmed by theoretical calculations based on their geometry established from scanning electron microscope (SEM) images. The chirality of the nanoshells is retained upon the release from the substrate into a stable dispersion. Deviation of the incident angle of light from normal results in increase of polarization rotation and chiral g-factor as high as -0.3. This general approach for preparation of abiological nanoscale chiral materials can be extended to other out-of plane 3D nanostructures. The large area films made on achiral nanopillars are convenient for sensors, optical devices, and catalysis. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Chiral Plasmonic Nanostructures on Achiral Nanopillars | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yeom, Bongjun | - |
dc.identifier.doi | 10.1021/nl402782d | - |
dc.identifier.scopusid | 2-s2.0-84887838757 | - |
dc.identifier.wosid | 000327111700044 | - |
dc.identifier.bibliographicCitation | NANO LETTERS, v.13, no.11, pp.5277 - 5283 | - |
dc.relation.isPartOf | NANO LETTERS | - |
dc.citation.title | NANO LETTERS | - |
dc.citation.volume | 13 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 5277 | - |
dc.citation.endPage | 5283 | - |
dc.type.rims | ART | - |
dc.type.docType | 정기학술지(Article(Perspective Article포함)) | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | INTENSE OPTICAL-ACTIVITY | - |
dc.subject.keywordPlus | CIRCULAR-DICHROISM | - |
dc.subject.keywordPlus | NANOPARTICLE SUPERSTRUCTURES | - |
dc.subject.keywordPlus | NANOROD DIMERS | - |
dc.subject.keywordPlus | DNA | - |
dc.subject.keywordPlus | NANOCRYSTALS | - |
dc.subject.keywordPlus | FABRICATION | - |
dc.subject.keywordPlus | ASSEMBLIES | - |
dc.subject.keywordPlus | SPECTRA | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordAuthor | Chirality | - |
dc.subject.keywordAuthor | plasmonic chirality | - |
dc.subject.keywordAuthor | ZnO | - |
dc.subject.keywordAuthor | nanopillars | - |
dc.subject.keywordAuthor | circular dichroism | - |
dc.subject.keywordAuthor | three-dimensional thin films | - |
dc.subject.keywordAuthor | 3D chirality | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/nl402782d | - |
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