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Generation of Zn2SiO4 Nanocrystallites in a Shell of ZnO/SiOx Core-Shell Nanowires to Change Photoluminescence Properties

Authors
Kim, Hyoun WooYang, Ju ChanNa, Han GilKwak, Dong SubLee, Chongmu
Issue Date
Aug-2012
Publisher
KOREAN INST METALS MATERIALS
Keywords
nanostructured materials; sputtering; optical properties; transmission electron microscopy (TEM); annealing
Citation
METALS AND MATERIALS INTERNATIONAL, v.18, no.4, pp.705 - 710
Indexed
SCIE
SCOPUS
KCI
Journal Title
METALS AND MATERIALS INTERNATIONAL
Volume
18
Number
4
Start Page
705
End Page
710
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/165000
DOI
10.1007/s12540-012-4021-z
ISSN
1598-9623
Abstract
This study addresses the annealing effects of ZnO/SiOx core-shell nanowire optical properties, in terms of Zn2SiO4 crystallite generation. At 700 A degrees C, the integrated PL intensity of deep-level emission was increased by annealing. With regard to UV emission, free exciton (FX) peak intensity was reduced and the ratio of FX to non-FX peak intensities increased as annealing temperature was increased. These annealing induced changes, including the enhancement of deep-level emission and suppression of FX emission, are mainly related to the generation of Zn2SiO4 crystallites. Transmission electron microscopy revealed that Zn2SiO4 crystallites were formed inside the SiOx shell layer.
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Kim, Hyoun Woo
COLLEGE OF ENGINEERING (SCHOOL OF MATERIALS SCIENCE AND ENGINEERING)
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