Technical benefits of using methane as a pyrolysis medium for catalytic pyrolysis of Kraft lignin
DC Field | Value | Language |
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dc.contributor.author | Farooq, Abid | - |
dc.contributor.author | Shiung Lam, Su | - |
dc.contributor.author | Hoon Rhee, Gwang | - |
dc.contributor.author | Lee, Jechan | - |
dc.contributor.author | Ali Khan, Moonis | - |
dc.contributor.author | Jeon, Byong-Hun | - |
dc.contributor.author | Park, Young-Kwon | - |
dc.date.accessioned | 2022-07-19T05:01:14Z | - |
dc.date.available | 2022-07-19T05:01:14Z | - |
dc.date.created | 2022-05-04 | - |
dc.date.issued | 2022-06 | - |
dc.identifier.issn | 0960-8524 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/170132 | - |
dc.description.abstract | Catalytic fast pyrolysis of low sulfonated Kraft lignin was performed under different atmospheric environments such as N2, CH4, and the gas derived from CH4 decomposition (CH4-D). The use of Zn- or Mo-loaded HZSM-5 as catalyst led to a higher pyrolytic oil yield compared to parent HZSM-5 in CH4 and CH4-D atmospheres. The yields of benzene, toluene, and xylenes were increased by the synergistic effects from metal loading, higher H/Ceff ratio, higher acidity, and CH4 activation. The enhanced CH4 activation via metal loading resulted in higher methylation of alkyl moieties and 33% increase in the total yield of benzene, toluene, and xylenes in comparison to parent HZSM-5. A higher H/Ceff ratio of 6 via CH4 decomposition led to the formation of a hydro-pyrolysis environment. Moreover, the CH4-D environment showed H2/CH4 ratio of 0.36 in the product gas which warranted the presence of more H2 under the CH4-D pyrolysis environment. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | Elsevier Ltd | - |
dc.title | Technical benefits of using methane as a pyrolysis medium for catalytic pyrolysis of Kraft lignin | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Jeon, Byong-Hun | - |
dc.identifier.doi | 10.1016/j.biortech.2022.127131 | - |
dc.identifier.scopusid | 2-s2.0-85128178863 | - |
dc.identifier.wosid | 000795623000001 | - |
dc.identifier.bibliographicCitation | Bioresource Technology, v.353, pp.1 - 6 | - |
dc.relation.isPartOf | Bioresource Technology | - |
dc.citation.title | Bioresource Technology | - |
dc.citation.volume | 353 | - |
dc.citation.startPage | 1 | - |
dc.citation.endPage | 6 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Agriculture | - |
dc.relation.journalResearchArea | Biotechnology & Applied Microbiology | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Agricultural Engineering | - |
dc.relation.journalWebOfScienceCategory | Biotechnology & Applied Microbiology | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.subject.keywordPlus | AROMATIC-HYDROCARBONS | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | BIOFUELS | - |
dc.subject.keywordPlus | BIOMASS | - |
dc.subject.keywordPlus | ZN | - |
dc.subject.keywordAuthor | Methane decomposition | - |
dc.subject.keywordAuthor | Aromatics | - |
dc.subject.keywordAuthor | Zeolites | - |
dc.subject.keywordAuthor | Kraft Lignin | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0960852422004606?via%3Dihub | - |
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