Asymmetric Divergent Total Syntheses of (+)-Decursivine and (+)-Serotobenine via Intramolecular Fischer Indole Synthesis
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Dong-Hyun | - |
dc.contributor.author | Kim, Hyo-Mi | - |
dc.contributor.author | Lim, Ji-Su | - |
dc.contributor.author | Lee, Hyun-Woo | - |
dc.contributor.author | Cho, C.-G. | - |
dc.date.accessioned | 2022-07-19T05:11:08Z | - |
dc.date.available | 2022-07-19T05:11:08Z | - |
dc.date.created | 2022-06-03 | - |
dc.date.issued | 2022-05 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/170235 | - |
dc.description.abstract | A new asymmetric synthetic route to (+)-decursivine and (+)-serotobenine is formulated. The key developments are the de novo construction of the crucial eight-membered 3,4-fused tricyclic indole ring engaged by the intramolecular Fischer indole synthesis and the stereocontrolled assembly of the dihydrobenzofuran subunit mediated by the asymmetric intramolecular Rh-carbenoid C-H insertion. BF3-mediated selective C15 epimerization followed by removal of the amine masking groups completed the target natural compounds' asymmetric and divergent total syntheses. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | American Chemical Society | - |
dc.title | Asymmetric Divergent Total Syntheses of (+)-Decursivine and (+)-Serotobenine via Intramolecular Fischer Indole Synthesis | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Cho, C.-G. | - |
dc.identifier.doi | 10.1021/acs.orglett.2c00848 | - |
dc.identifier.scopusid | 2-s2.0-85128799800 | - |
dc.identifier.wosid | 000794996900018 | - |
dc.identifier.bibliographicCitation | Organic Letters, v.24, no.15, pp.2873 - 2877 | - |
dc.relation.isPartOf | Organic Letters | - |
dc.citation.title | Organic Letters | - |
dc.citation.volume | 24 | - |
dc.citation.number | 15 | - |
dc.citation.startPage | 2873 | - |
dc.citation.endPage | 2877 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | COMBINATION | - |
dc.subject.keywordPlus | (+/-)-SEROTOBENINE | - |
dc.subject.keywordPlus | (+/-)-DECURSIVINE | - |
dc.subject.keywordPlus | DECURSIVINE | - |
dc.subject.keywordPlus | MOSCHAMINE | - |
dc.subject.keywordPlus | ALKALOIDS | - |
dc.subject.keywordPlus | INSERTION | - |
dc.subject.keywordPlus | CLEAVAGE | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acs.orglett.2c00848 | - |
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