Correlations between phase behaviors and ionic conductivities of (ionic liquid plus alcohol) systems
- Authors
- Park, Nam Ku; Bae, Young Chan
- Issue Date
- Nov-2010
- Publisher
- ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
- Keywords
- Ionic liquids; Lattice model; Phase behavior; (Vapor plus liquid) equilibria; Specific interactions; Ionic conductivity
- Citation
- JOURNAL OF CHEMICAL THERMODYNAMICS, v.42, no.11, pp.1316 - 1323
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF CHEMICAL THERMODYNAMICS
- Volume
- 42
- Number
- 11
- Start Page
- 1316
- End Page
- 1323
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/173505
- DOI
- 10.1016/j.jct.2010.05.012
- ISSN
- 0021-9614
- Abstract
- To understand the basic properties of ionic liquids (ILs), we examined the phase behavior and ionic conductivity characteristics using various compositions of different ionic liquids (1-ethy1-3-methylimidazolium hexafluorophosphate [emim] [PF6] and 1-benzyl-3-methylimidazolium hexafluorophosphate [bzmim] [PF6]) in several different alcohols (ethanol, propanol, 1-butanol, 2-butanol, and hexanol). We conducted a systematic study of the impact of different factors on the phase behavior of imidazolium-based ionic liquids in alcohols. Using a new experimental method with a liquid electrolyte system, we observed that the ionic conductivity of the ionic liquid/alcohol was sensitive to the surrounding temperature. We employed Chang et al.'s thermodynamic model [Chang et al. (1997, 1998) [21,22]] based on the lattice model. The obtained co-ordinated unit parameter from this model was used to describe the phase behavior and ionic conductivities of the given system. Good agreement with experimental data of various alcohol and Its systems was obtained in the range of interest.
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