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Gold-catalyzed cyclization of enyne-1,6-diols to substituted furans

Authors
Kim, SundaeKang, DongjinShin, SeunghoonLee, Phil Ho
Issue Date
Apr-2010
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
TETRAHEDRON LETTERS, v.51, no.14, pp.1899 - 1901
Indexed
SCIE
SCOPUS
Journal Title
TETRAHEDRON LETTERS
Volume
51
Number
14
Start Page
1899
End Page
1901
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/175201
DOI
10.1016/j.tetlet.2010.02.026
ISSN
0040-4039
Abstract
Treatment of enyne-1,6-diols with 5 mol % Ph3PAuCl in the presence of 5 mol % AgOTf as a cocatalyst selectively produced trisubstituted furans in good to excellent yields in dichloromethane at room temperature for 5-10 min through cyclization followed by isomerization.
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