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Pt-Catalyzed Hydrative Cyclization of 2-Enynylbenzaldehydes and Its Application to Faveline Synthesis
- Authors
- Oh, Chang Ho; Lee, Sung Min; Hong, Chang Seop
- Issue Date
- Mar-2010
- Publisher
- American Chemical Society
- Citation
- Organic Letters, v.12, no.6, pp 1308 - 1311
- Pages
- 4
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- Organic Letters
- Volume
- 12
- Number
- 6
- Start Page
- 1308
- End Page
- 1311
- ISSN
- 1523-7060
1523-7052
- Abstract
- Various 2-[6-en-1-ynyl]benzaldehydes and their analogues were successfully cyclized via Huisgen-type [3+2] cycloaddition to the tetracyclic platinum-carbene complex, which would subsequently undergo hydration to afford the tricyclic products in good yields with excellent stereoselectivities. This hydrative cyclization was also applied to the faveline synthesis.
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