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Total syntheses of (+/-)-crinine, (+/-)-crinamine, and (+/-)-6a-epi-crinamine via the regioselective synthesis and Diels-Alder reaction of 3-aryl-5-bromo-2-pyrone
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Tam, Nguyen Thanh | - |
| dc.contributor.author | Chang, Jayhyok | - |
| dc.contributor.author | Jung, Eun-Ju | - |
| dc.contributor.author | Cho, Cheon-Gyu | - |
| dc.date.accessioned | 2022-12-21T01:49:17Z | - |
| dc.date.available | 2022-12-21T01:49:17Z | - |
| dc.date.issued | 2008-08 | - |
| dc.identifier.issn | 0022-3263 | - |
| dc.identifier.issn | 1520-6904 | - |
| dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/178109 | - |
| dc.description.abstract | [GRAPHICS] We have devised a new unified synthetic protocol to (+/-)-crinine, (+/-)-crinamine, and (+/-)-6a-epi-crinamine from the Diels-Alder cycloadduct of 3-(3,4-methylenedioxyphenyl)-5-bromo-2-pyrone with TBS vinyl ether. The requisite 3-(3,4-methylenedioxyphenyl)-5-bromo-2-pyrone was prepared from the C3-selective Stille coupling reaction of 3,5-dibromo-2-pyrone. Also noted is that the vinyl bromide can be used as a handle for further derivatization. | - |
| dc.format.extent | 7 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | American Chemical Society | - |
| dc.title | Total syntheses of (+/-)-crinine, (+/-)-crinamine, and (+/-)-6a-epi-crinamine via the regioselective synthesis and Diels-Alder reaction of 3-aryl-5-bromo-2-pyrone | - |
| dc.type | Article | - |
| dc.publisher.location | 미국 | - |
| dc.identifier.doi | 10.1021/jo8008353 | - |
| dc.identifier.scopusid | 2-s2.0-50149083686 | - |
| dc.identifier.wosid | 000258332500027 | - |
| dc.identifier.bibliographicCitation | The Journal of Organic Chemistry, v.73, no.16, pp 6258 - 6264 | - |
| dc.citation.title | The Journal of Organic Chemistry | - |
| dc.citation.volume | 73 | - |
| dc.citation.number | 16 | - |
| dc.citation.startPage | 6258 | - |
| dc.citation.endPage | 6264 | - |
| dc.type.docType | Article | - |
| dc.description.isOpenAccess | N | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.subject.keywordPlus | AZA-COPE REARRANGEMENTS | - |
| dc.subject.keywordPlus | AMARYLLIDACEAE ALKALOIDS | - |
| dc.subject.keywordPlus | CYCLOADDITIONS | - |
| dc.subject.keywordPlus | TANDEM | - |
| dc.subject.keywordPlus | CIS-3A-ARYLOCTAHYDROINDOLES | - |
| dc.subject.keywordPlus | 3,5-DIBROMO-2-PYRONE | - |
| dc.subject.keywordPlus | (-)-HAEMANTHIDINE | - |
| dc.subject.keywordPlus | (-)-AMABILINE | - |
| dc.subject.keywordPlus | CRININE | - |
| dc.subject.keywordPlus | ROUTE | - |
| dc.identifier.url | https://pubs.acs.org/doi/10.1021/jo8008353 | - |
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Related Researcher
- Cho, Cheon Gyu
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)