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Synthesis and electrochemical properties of Li[Ni0.45Co0.1Mn0.45-xZrx]O-2 (x=0, 0.02) via co-precipitation method

Authors
Bang, Hyun JooPark, Byung-ChonPrakash, JaiSun, Yang Kook
Issue Date
Dec-2007
Publisher
ELSEVIER SCIENCE BV
Keywords
co-precipitation; cathode; lithium ion battery; zirconium
Citation
JOURNAL OF POWER SOURCES, v.174, no.2, pp.565 - 568
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF POWER SOURCES
Volume
174
Number
2
Start Page
565
End Page
568
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/179297
DOI
10.1016/j.jpowsour.2007.06.122
ISSN
0378-7753
Abstract
Li[Ni0.45Co0.1Mn0.45-xZrx]O-2 (x = 0, 0.02) was synthesized via co-precipitation method. Partial Zr doping on the host structure of Li[Ni0.45Co0.1Mn0.45]O-2 was carried out to improve the electrochemical properties. The Zr-doped Li[Ni0.45Co0.1Mn0.43Zr0.02]O-2 was evaluated in terms of specific discharge capacity, cycling performance and thermal stability. The Zr-doped Li[Ni0.45Co0.1Mn0.45-xZr0.02]O-2 shows the improved cycling performance and stable thermal stability. The major exothermic reaction was delayed from 252.1 degrees C to 289.4 degrees C.
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