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Au(I)-catalyzed tandem [3,3]-sigmatropic rearrangement-cycloisomerization cascade as a route to spirocyclic furans

Authors
Yeom, Hyun SukYoon, Suk JaeShin, Seunghoon
Issue Date
Jul-2007
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
TETRAHEDRON LETTERS, v.48, no.28, pp.4817 - 4820
Indexed
SCIE
SCOPUS
Journal Title
TETRAHEDRON LETTERS
Volume
48
Number
28
Start Page
4817
End Page
4820
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/179904
DOI
10.1016/j.tetlet.2007.05.067
ISSN
0040-4039
Abstract
Gold-catalyzed reaction of 1-(3-hydroxypropynyl)cycloalkanol derivatives was studied. The reaction profile was highly dependent on the ring size, migrating group, as well as reaction conditions. An efficient route to spirocyclic furans via tandem (3,3]-sigmatropic rearrangement-cycloisomerization is reported.
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COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)
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