Temperature-Dependent n-to-p-Type Transition of 2D Mn Oxide Nanosheets toward NO2 for Flexible Gas Sensor Application
- Authors
- Kim, Dong-Ha; Lee, Joon-Seok; Park, Hee Jung; Kim, Il-Doo; Choi, Seon-Jin
- Issue Date
- Jan-2023
- Publisher
- AMER CHEMICAL SOC
- Keywords
- 2D materials; Mn oxide nanosheets; NO2 sensor; Ag nanotube; flexible heater
- Citation
- ACS SENSORS, v.8, no.1, pp.280 - 288
- Indexed
- SCIE
SCOPUS
- Journal Title
- ACS SENSORS
- Volume
- 8
- Number
- 1
- Start Page
- 280
- End Page
- 288
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/185086
- DOI
- 10.1021/acssensors.2c02181
- ISSN
- 2379-3694
- Abstract
- Rapid and on-site detection of nitrogen dioxide (NO2) is important for environmental monitoring as NO2 is a highly toxic chemical emitted from automobiles and power plants. In this study, we proposed atomically thin two-dimensional (2D) Mn oxide nanosheets (NSs) assembled on a flexible heating substrate for application in flexible and wearable NO2 sensors. A liquid-phase exfoliation technique was used to obtain individual Mn oxide layers that formed a homogeneous suspension. A flexible heater was fabricated by partially embedding Ag nanotubes (NTs) on the surface of a colorless polyimide (CPI) film for use as a sensor substrate. Temperature-dependent NO2 sensing properties were investigated via control of the operating temperature using a Ag NT-embedded CPI heating film. As a result, the n-type sensing behavior of the Mn oxide NSs exhibited a response [(Rgas - Rair)/Rair x 100 (%)] of 1.20 +/- 0.21% for 20 ppm NO2 at room temperature (25 degrees C). Meanwhile, n-p transition occurred with p-type sensing property as the operating temperature increased to 150 degrees C with an improved response [(Rair - Rgas)/Rair x 100 (%)] of 4.10 +/- 0.42% for 20 ppm NO2. The characteristic n-p transition of Mn oxide NSs at different operating temperatures was evidenced by the surface-adsorbed oxygen ions (i.e., O2- and O-) and nitrate species (NO3- and NO32-).
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