alpha-Carbonyl Radicals from N-Enoxybenzotriazoles: De Novo Synthesis of 9-Phenanthrols
DC Field | Value | Language |
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dc.contributor.author | Nguyen, Quynh H. | - |
dc.contributor.author | Um, Tae-Woong | - |
dc.contributor.author | Shin, Seunghoon | - |
dc.date.accessioned | 2023-05-03T11:21:35Z | - |
dc.date.available | 2023-05-03T11:21:35Z | - |
dc.date.created | 2022-12-07 | - |
dc.date.issued | 2022-11 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/185228 | - |
dc.description.abstract | Visible-light-induced energy transfer to N-enoxybenzotriazoles in the presence of hydrogen atom donors or alcoholic solvents led to alpha-carbonyl radicals. The utility of the alpha-carbonyl radicals was demonstrated in intramolecular tandem cyclization and in the synthesis of 9-phenanthrols and their analogues. The mechanistic experiments suggested that quenching of the reactive benzotriazolyl radical by the alcohol was accompanied by the formation of an alpha-hydroxy radical that mediated hydrogen atom transfer or, itself, oxidized into aldehydes. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | alpha-Carbonyl Radicals from N-Enoxybenzotriazoles: De Novo Synthesis of 9-Phenanthrols | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Shin, Seunghoon | - |
dc.identifier.doi | 10.1021/acs.orglett.2c03356 | - |
dc.identifier.scopusid | 2-s2.0-85141706474 | - |
dc.identifier.wosid | 000882603400001 | - |
dc.identifier.bibliographicCitation | ORGANIC LETTERS, v.24, no.45, pp.8337 - 8342 | - |
dc.relation.isPartOf | ORGANIC LETTERS | - |
dc.citation.title | ORGANIC LETTERS | - |
dc.citation.volume | 24 | - |
dc.citation.number | 45 | - |
dc.citation.startPage | 8337 | - |
dc.citation.endPage | 8342 | - |
dc.type.rims | ART | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | ENERGY-TRANSFER | - |
dc.subject.keywordPlus | AROMATIC-HYDROCARBONS | - |
dc.subject.keywordPlus | CYCLIZATION | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | ACCESS | - |
dc.subject.keywordPlus | PHOTOSENSITIZATION | - |
dc.subject.keywordPlus | FUNCTIONALIZATIONS | - |
dc.subject.keywordPlus | ALKENES | - |
dc.subject.keywordPlus | SALTS | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acs.orglett.2c03356 | - |
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