Dendrite Suppression Membranes for Rechargeable Zinc Batteries
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Byoung-Sun | - |
dc.contributor.author | Cui, Shuang | - |
dc.contributor.author | Xing, Xing | - |
dc.contributor.author | Liu, Haodong | - |
dc.contributor.author | Yue, Xiujun | - |
dc.contributor.author | Petrova, Victoria | - |
dc.contributor.author | Lim, Hee-Dae | - |
dc.contributor.author | Chen, Renkun | - |
dc.contributor.author | Liu, Ping | - |
dc.date.accessioned | 2023-07-24T09:59:42Z | - |
dc.date.available | 2023-07-24T09:59:42Z | - |
dc.date.created | 2023-07-04 | - |
dc.date.issued | 2018-11 | - |
dc.identifier.issn | 1944-8244 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/187550 | - |
dc.description.abstract | Aqueous batteries with zinc metal anodes are promising alternatives to Li-ion batteries for grid storage because of their abundance and benefits in cost, safety, and nontoxicity. However, short cyclability due to zinc dendrite growth remains a major obstacle. Here, we report a cross-linked polyacrylonitrile (PAN)-based cation exchange membrane that is low cost and mechanically robust. Li2S3 reacts with PAN, simultaneously leading to cross-linking and formation of sulfur-containing functional groups. Hydrolysis of the membrane results in the formation of a membrane that achieves preferred cation transport and homogeneous ionic flux distribution. The separator is thin (30 mu m-thick), almost 9 times stronger than hydrated Nafion, and made of low-cost materials. The membrane separator enables exceptionally long cyclability (>350 cycles) of Zn/Zn symmetric cells with low polarization and effective dendrite suppression. Our work demonstrates that the design of new separators is a fruitful pathway to enhancing the cyclability of aqueous batteries. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Dendrite Suppression Membranes for Rechargeable Zinc Batteries | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Lim, Hee-Dae | - |
dc.identifier.doi | 10.1021/acsami.8b14022 | - |
dc.identifier.scopusid | 2-s2.0-85056509006 | - |
dc.identifier.wosid | 000451100500029 | - |
dc.identifier.bibliographicCitation | ACS APPLIED MATERIALS & INTERFACES, v.10, no.45, pp.38928 - 38935 | - |
dc.relation.isPartOf | ACS APPLIED MATERIALS & INTERFACES | - |
dc.citation.title | ACS APPLIED MATERIALS & INTERFACES | - |
dc.citation.volume | 10 | - |
dc.citation.number | 45 | - |
dc.citation.startPage | 38928 | - |
dc.citation.endPage | 38935 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | LITHIUM-SULFUR BATTERY | - |
dc.subject.keywordPlus | DOPED CARBON DOTS | - |
dc.subject.keywordPlus | SOLID-STATE | - |
dc.subject.keywordPlus | ALKALINE BATTERIES | - |
dc.subject.keywordPlus | EXCHANGE MEMBRANES | - |
dc.subject.keywordPlus | HIGH-CAPACITY | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | POLYACRYLONITRILE | - |
dc.subject.keywordPlus | ELECTROLYTE | - |
dc.subject.keywordPlus | CATHODE | - |
dc.subject.keywordAuthor | aqueous battery separator | - |
dc.subject.keywordAuthor | dendrite growth suppression | - |
dc.subject.keywordAuthor | zinc battery | - |
dc.subject.keywordAuthor | ion flux distribution | - |
dc.subject.keywordAuthor | single-ion transport | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acsami.8b14022 | - |
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