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CuWO4 as a cost-effective electrocatalyst for urea oxidation reaction

Authors
Sreekanth, Thupakula Venkata MadhukarPrasad, KumchamYoo, JihyungKim, JonghoonYoo, Kisoo
Issue Date
Aug-2023
Publisher
ELSEVIER
Keywords
Surfactants; Hydrothermal; Electrocatalyst; UOR; CuWO4
Citation
INORGANIC CHEMISTRY COMMUNICATIONS, v.154, pp.1 - 7
Indexed
SCIE
SCOPUS
Journal Title
INORGANIC CHEMISTRY COMMUNICATIONS
Volume
154
Start Page
1
End Page
7
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/188969
DOI
10.1016/j.inoche.2023.110933
ISSN
1387-7003
Abstract
The urea oxidation reaction (UOR) plays a critical role in hydrogen (H2) production and in purifying urea-rich wastewater. However, the widespread application of UOR is restricted by the scarcity of low-cost and efficient electrocatalysts. In this study, inexpensive copper tungstate (CuWO4) catalysts were successfully synthesized using a simple hydrothermal synthesis method in the presence of cetrimonium bromide (CTAB) and polyvinylpyrrolidone (PVP) surfactants; the synthesized electrocatalysts were denoted as CW-2 and CW-3, respectively. CW-2 and CW-3 were analyzed via XRD, XPS, FTIR, SEM, and TEM. The CW-3 electrocatalyst shows the lower (430 mV) overpotential, compared with CW-2 electrocatalyst (486 mV) in OER analysis.
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