1,2-Phenylene-Incorporated Smallest Expanded Calix[4]pyrrole via One-Step Synthesis of Tetrapyrrane: A Fluorescent Host for Fluoride Ion
DC Field | Value | Language |
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dc.contributor.author | Kumar, B. Sathish | - |
dc.contributor.author | Chandra, Brijesh | - |
dc.contributor.author | Jose, K. V. Jovan | - |
dc.contributor.author | Panda, Pradeepta K. | - |
dc.date.accessioned | 2023-09-04T07:16:01Z | - |
dc.date.available | 2023-09-04T07:16:01Z | - |
dc.date.created | 2023-07-21 | - |
dc.date.issued | 2021-08 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/189711 | - |
dc.description.abstract | Synthesis of tetrapyrrane 8 from acetone and pyrrole via one-step condensation was achieved for the first time along with a much-improved yield of the tripyrrane 9. Diborylation of the tetrapyrrane and subsequent "1 + 1" cyclocoupling with 1,2-diiodobenzene following the Suzuki protocol generated novel o-phenylene incorporated macrocycle belonging to the smallest mesoexpanded calix[4]pyrrole family. The latter macrocycle displays exclusive turn-on fluorescence sensing of fluoride ion upon complexation via a unique partial cone conformation supported by DFT analysis in acetonitrile solvent. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | 1,2-Phenylene-Incorporated Smallest Expanded Calix[4]pyrrole via One-Step Synthesis of Tetrapyrrane: A Fluorescent Host for Fluoride Ion | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kumar, B. Sathish | - |
dc.identifier.doi | 10.1021/acs.joc.1c01179 | - |
dc.identifier.scopusid | 2-s2.0-85112689219 | - |
dc.identifier.wosid | 000684025500058 | - |
dc.identifier.bibliographicCitation | JOURNAL OF ORGANIC CHEMISTRY, v.86, no.15, pp.10536 - 10543 | - |
dc.relation.isPartOf | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.title | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 86 | - |
dc.citation.number | 15 | - |
dc.citation.startPage | 10536 | - |
dc.citation.endPage | 10543 | - |
dc.type.rims | ART | - |
dc.type.docType | 정기학술지(Article(Perspective Article포함)) | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | SOLVENT-FREE CONDENSATION | - |
dc.subject.keywordPlus | ANION-BINDING PROPERTIES | - |
dc.subject.keywordPlus | RECOGNITION | - |
dc.subject.keywordPlus | PYRROLE | - |
dc.subject.keywordPlus | CALIXPYRROLES | - |
dc.subject.keywordPlus | MACROCYCLES | - |
dc.subject.keywordPlus | PORPHYRIN | - |
dc.subject.keywordPlus | FURAN | - |
dc.subject.keywordPlus | CALIXPHYRINS | - |
dc.subject.keywordPlus | RECEPTORS | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acs.joc.1c01179 | - |
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