Recent advances in the synthesis of heterocycles and pharmaceuticals from the photo-electrochemical fixation of carbon dioxide
- Authors
- Hoang Long Ngo; Mishra, Dinesh Kumar; Mishra, Vivek; Cong Chien Truong
- Issue Date
- Jan-2021
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- CO2 fixation; Photochemical; Electrochemical; Synthesis of Heterocycles and Pharmaceuticals
- Citation
- CHEMICAL ENGINEERING SCIENCE, v.229
- Indexed
- SCIE
SCOPUS
- Journal Title
- CHEMICAL ENGINEERING SCIENCE
- Volume
- 229
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/189723
- DOI
- 10.1016/j.ces.2020.116142
- ISSN
- 0009-2509
- Abstract
- In recent years, the deployment of carbon dioxide (CO2) as a renewable and benign building block in the assembly of bioactive heterocycles and pharmaceuticals has become one of the most appealing topics in the CO2 utilization. In this context, the photo/electrochemical approaches are acknowledged as powerful toolkits in the manufacture of CO2-based heterocycles and pharmaceuticals, which enables the CO2 valorization to take place in a more mild-mannered and eco-friendly conditions with respect to other chemical patterns. In this review, several typical examples on the photo/electrochemical fixation of CO2 into divergent heterocyclic scaffolds and important pharmaceuticals are highlighted. Furthermore, the detailed mechanistic descriptions of various synthetic paradigms are also described to provide a better understanding on the success of these strategies.
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