Insight into pulse-charging for lithium plating-free fast-charging lithium-ion batteries
- Authors
- Jeong, Yeon Tae; Shin, Hong Rim; Lee, Jinhong; Ryu, Myung-Hyun; Choi, Sinho; Kim, Hansung; Jung, Kyu-Nam; Lee, Jong-Won
- Issue Date
- Sep-2023
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- Lithium -ion battery; Fast -charging; Lithium plating; Pulse -charging; Charging protocol
- Citation
- ELECTROCHIMICA ACTA, v.462, pp.1 - 8
- Indexed
- SCIE
SCOPUS
- Journal Title
- ELECTROCHIMICA ACTA
- Volume
- 462
- Start Page
- 1
- End Page
- 8
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/190546
- DOI
- 10.1016/j.electacta.2023.142761
- ISSN
- 0013-4686
- Abstract
- In recent years, tremendous efforts have been devoted to searching for the fast-charging methodology of lithiumion battery (LIB) with widespread practical application of the electric vehicles, since the uncontrolled Li plating on the graphite anode under the fast-charging condition can lead the accelerated capacity decay and cause the safety issues of LIB. Here, we present mechanistic insights into the pulse-current-based fast-charging to aid with suppressing Li plating on the graphite anode. Compared with a conventional fast-charging protocol of the constant current method, the full-cell assembled with graphite anode and LiNi0.6Co0.2Mn0.2O2 cathode exhibits the improved fast-charging capability and cycle performance under the pulse-charging protocol. In particular, the graphite anode after prolonged 300 cycles shows a clean surface free of plated Li, which confirms that the pulse-charging protocol effectively inhibits Li plating on the anode even under fast-charging conditions. Furthermore, the physics-based numerical modeling results demonstrate that the pulse-current redistributes the accumulated Li+ species at the electrolyte/anode interface periodically, which mitigates the anode potential drop and prevents consequent Li plating.
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