The production of debrominated aromatics via the catalytic pyrolysis of flexible printed circuit boards
DC Field | Value | Language |
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dc.contributor.author | Pyo, Sumin | - |
dc.contributor.author | Kumar, Avnish | - |
dc.contributor.author | Ali Khan, Moonis | - |
dc.contributor.author | Jeon, Byong-Hun | - |
dc.contributor.author | Choi, Siyoung Q. | - |
dc.contributor.author | Kim, Young-Min | - |
dc.contributor.author | Park, Young-Kwon | - |
dc.date.accessioned | 2023-09-18T06:22:10Z | - |
dc.date.available | 2023-09-18T06:22:10Z | - |
dc.date.created | 2023-08-01 | - |
dc.date.issued | 2023-09 | - |
dc.identifier.issn | 1385-8947 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/190554 | - |
dc.description.abstract | Pyrolysis is an environmental technology for the proper treatment of electronic waste (e-waste) for the production of fuel. However, the presence of brominated compounds in pyrolysis oil makes its commercialization difficult. In this study, various types of zeolites, HY (30), HZSM-5 (30), HZSM-5 (50), HZSM-5 (280), and basic metal oxides (MgO and CaO) were used for the pyrolysis of flexible printed circuit boards (FPCBs) for the first time to produce bromine-free oil. A higher production efficiency of debrominated aromatic hydrocarbons, primarily benzene, toluene, ethylbenzene, xylenes (BTEXs), and naphthalene with zeolites, was achieved over basic metal oxides. The use of HZSM-5 (HZ) (30) increased the amount of benzene (an area of 31.5 × 107) and toluene (an area of 17.6 × 107), and a high debromination efficiency was observed for basic metal oxides owing to the strong affinity of halides toward the Ca2+ and Mg2+ ions. Among the BTEXs, benzene (an area of 31.5 × 107) and toluene (an area of 17.6 × 107) were obtained as highly selective monoaromatics in the presence of the catalyst HZ (30). CaO and HZ (30) were effective for debromination and aromatic production, respectively. The in-situ CaO/ex-situ HZ (30) combination revealed ∼ 100% debromination efficiency; however, the total aromatic hydrocarbon production was higher on the in-situ HZ (30)/ex-situ CaO with ∼ 77.5% debromination efficiency. Meanwhile, the in-situ HZ (30)/ex-situ CaO configuration could achieve ∼ 100% debromination efficiency by increasing the amount of CaO to 7 times to feed. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.title | The production of debrominated aromatics via the catalytic pyrolysis of flexible printed circuit boards | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Jeon, Byong-Hun | - |
dc.identifier.doi | 10.1016/j.cej.2023.144783 | - |
dc.identifier.scopusid | 2-s2.0-85165560696 | - |
dc.identifier.wosid | 001047229500001 | - |
dc.identifier.bibliographicCitation | CHEMICAL ENGINEERING JOURNAL, v.472, pp.1 - 14 | - |
dc.relation.isPartOf | CHEMICAL ENGINEERING JOURNAL | - |
dc.citation.title | CHEMICAL ENGINEERING JOURNAL | - |
dc.citation.volume | 472 | - |
dc.citation.startPage | 1 | - |
dc.citation.endPage | 14 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | THERMAL-DECOMPOSITION | - |
dc.subject.keywordPlus | CO-PYROLYSIS | - |
dc.subject.keywordPlus | OIL | - |
dc.subject.keywordPlus | CAO | - |
dc.subject.keywordPlus | WASTE | - |
dc.subject.keywordPlus | MGO | - |
dc.subject.keywordPlus | MICROALGAE | - |
dc.subject.keywordPlus | OXYGEN | - |
dc.subject.keywordPlus | PCBS | - |
dc.subject.keywordPlus | FE | - |
dc.subject.keywordAuthor | Flexible printed circuit board | - |
dc.subject.keywordAuthor | Zeolites | - |
dc.subject.keywordAuthor | Basic metal oxides | - |
dc.subject.keywordAuthor | Aromatics | - |
dc.subject.keywordAuthor | Debromination | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S1385894723035143?via%3Dihub | - |
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